Polarographic Study of the Effect of Gelatin on the Kinetics of Irreversible Electrode Processes

Jacob E. Strassner; Paul Delahay

doi:10.1021/ja01144a023

Polarographic Study of the Effect of Gelatin on the Kinetics of Irreversible Electrode Processes

Journal of the American Chemical Society ◽

10.1021/ja01144a023 ◽

1952 ◽

Vol 74 (24) ◽

pp. 6232-6235 ◽

Cited By ~ 14

Author(s):

Jacob E. Strassner ◽

Paul Delahay

Keyword(s):

Polarographic Study ◽

Electrode Processes ◽

Kinetics Of

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Kinetics of electrode processes. IX. Electrolysis with an antecedent chemical reaction

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19540210 ◽

1954 ◽

Vol 19 (2) ◽

pp. 210-220 ◽

Cited By ~ 1

Author(s):

J. Plíva ◽

M. Smutek

Keyword(s):

Chemical Reaction ◽

Electrode Processes ◽

Kinetics Of

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Polarographic study of the kinetics of the reaction of divalent maleic acid anion with proton donors

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19603025 ◽

1960 ◽

Vol 25 (12) ◽

pp. 3025-3035 ◽

Cited By ~ 25

Author(s):

S. G. Mairanovskii ◽

L. I. Lishcheta

Keyword(s):

Maleic Acid ◽

Polarographic Study ◽

Acid Anion ◽

Proton Donors ◽

Kinetics Of

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Study of the kinetics of electrode processes by means of electrolysis with constant current. XII. A chemical change of the electroreduction product to a reversibly oxidizable substance

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19682370 ◽

1968 ◽

Vol 33 (8) ◽

pp. 2370-2380 ◽

Cited By ~ 2

Author(s):

O. Fischer ◽

O. Dračka ◽

J. V. Stenina-Jakovleva

Keyword(s):

Chemical Change ◽

Constant Current ◽

Electrode Processes ◽

Kinetics Of

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Study of the kinetics of electrode processes by means of electrolysis with constant current. XI. Irreversible consecutive two-step reaction of first order

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc19673987 ◽

1967 ◽

Vol 32 (11) ◽

pp. 3987-3997 ◽

Cited By ~ 4

Author(s):

O. Dračka

Keyword(s):

Constant Current ◽

First Order ◽

Electrode Processes ◽

Kinetics Of

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Kinetics of Electrode Processes of LiFePO4 in Saturated Lithium Nitrate Solution

Acta Physico-Chimica Sinica ◽

10.3866/pku.whxb20070127 ◽

2007 ◽

Vol 23 (01) ◽

pp. 129-133

Author(s):

HUANG Ke-Long ◽

◽

YANG Sai ◽

LIU Su-Qin ◽

...

Keyword(s):

Nitrate Solution ◽

Lithium Nitrate ◽

Electrode Processes ◽

Kinetics Of

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Kinetics of the electrode processes of complexes in polarography. IV. Polarographic behaviour of monovalent thallium in solutions of ethylenediamine tetraacetic acid (in German).

Journal of Electroanalytical Chemistry (1959) ◽

10.1016/0022-0728(60)85194-7 ◽

1960 ◽

Vol 1 (5) ◽

pp. A45-A46

Keyword(s):

Tetraacetic Acid ◽

Electrode Processes ◽

Ethylenediamine Tetraacetic Acid ◽

Polarographic Behaviour ◽

Kinetics Of

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Kinetics of electrode processes on the iron electrode

Discussions of the Faraday Society ◽

10.1039/df9470100259 ◽

1947 ◽

Vol 1 ◽

pp. 259 ◽

Cited By ~ 132

Author(s):

B. Kabanov ◽

R. Burstein ◽

A. Frumkin

Keyword(s):

Iron Electrode ◽

Electrode Processes ◽

Kinetics Of

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Kinetics of the oxidation of dimethyl sulfoxide with aqueous hydrogen peroxide catalyzed by sodium tungstate

Canadian Journal of Chemistry ◽

10.1139/v81-104 ◽

1981 ◽

Vol 59 (4) ◽

pp. 718-722 ◽

Cited By ~ 20

Author(s):

Yoshiro Ogata ◽

Kazushige Tanaka

Keyword(s):

Hydrogen Peroxide ◽

Dimethyl Sulfoxide ◽

Sodium Tungstate ◽

Catalytic Amount ◽

Active Oxygen ◽

Probable Mechanism ◽

Polarographic Study ◽

Aqueous Hydrogen Peroxide ◽

First Order ◽

Kinetics Of

The oxidation of dimethyl sulfoxide (DMSO) by hydrogen peroxide in the presence of a catalytic amount of sodium tungstate (Na2WO4) has been studied kinetically by means of iodometry of hydrogen peroxide. The reaction is first-order with respect to the substrate and the catalyst, but independent of the concentration of hydrogen peroxide which is present in excess of the catalyst. The polarographic study implies that in solutions two main kinds of peroxytungstic acids (H2WO5 and H2WO8) are formed which contain active oxygen in ratios (active oxygen):(Na2WO4) of 1:1 and 4:1, respectively. The effect of acidity on the oxidation rate and a probable mechanism involving a rate-determining attack of peroxytungstic acids are discussed.

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