Addition Reactions of Nitroalkanes with Acrolein and Methyl Vinyl Ketone. Selective Reduction of Nitrocarbonyl Compounds to Nitrocarbinols

1952 ◽  
Vol 74 (14) ◽  
pp. 3664-3668 ◽  
Author(s):  
Harold Shechter ◽  
Dean E. Ley ◽  
Lawrence Zeldin
Keyword(s):  
Selective Reduction ◽  
Vinyl Ketone ◽  
Methyl Vinyl Ketone ◽  
Addition Reactions ◽  
Methyl Vinyl

Aprotic Conjugate Addition Reactions of Lithiated Allylic Sulfoxides With Acyclic Enones; a Breakdown of the trans-Decalyl Transition State

1989 ◽  
Vol 42 (10) ◽  
pp. 1785 ◽  
Author(s):  
RK Haynes ◽  
AG Katsifis ◽  
LM King ◽  
SC Vonwiller
Keyword(s):  
Transition State ◽  
Conjugate Addition ◽  
Vinyl Ketone ◽  
Methyl Vinyl Ketone ◽  
Mesityl Oxide ◽  
Addition Reactions ◽  
State Characteristic ◽  
Methyl Vinyl ◽  
Cyclic Enones ◽  
Carbonyl Addition

The reactions of lithiated 1-(t-butylsulfinyl)prop-2-ene, 1-(t-butylsulfinyl)-3-methylbut-2-ene, 1-(t-butylsulfinyl)but-2-ene, 1-(phenylsulfinyl)but-2-ene and 2-methyl-1-(phenylsu1finyl)prop- 2-ene with methyl vinyl ketone, mesityl oxide and crotonaldehyde give largely carbonyl addition products arising from reaction through C1 or C3 of the allyl system. In the case of methyl crotonate, conjugate addition through C3 is observed. The initially formed diastereomers of the C1 adducts, allylic sulfoxides, are configurationally unstable. Only the lithiated 1-(t-butylsulfinyl)-3-methylbut-2-ene undergoes conjugate addition with methyl vinyl ketone to give an (E)-vinyl sulfoxide whose formation may involve the trans-decalyl transition state characteristic of the reactions of lithiated allylic sulfoxides with cyclic enones.

Gold(III) Chloride-Catalyzed Addition Reactions of Electron-Rich Arenes to Methyl Vinyl Ketone.

ChemInform ◽  
2004 ◽  
Vol 35 (11) ◽  
Author(s):  
Gerald Dyker ◽  
Enrico Muth ◽  
A. Stephen K. Hashmi ◽  
Li Ding
Keyword(s):  
Vinyl Ketone ◽  
Methyl Vinyl Ketone ◽  
Addition Reactions ◽  
Methyl Vinyl

Gold(III) Chloride-Catalyzed Addition Reactions of Electron-Rich Arenes to Methyl Vinyl Ketone

2003 ◽  
Vol 345 (11) ◽  
pp. 1247-1252 ◽  
Author(s):  
Gerald Dyker ◽  
Enrico Muth ◽  
A. Stephen K. Hashmi ◽  
Li Ding
Keyword(s):  
Vinyl Ketone ◽  
Methyl Vinyl Ketone ◽  
Addition Reactions ◽  
Methyl Vinyl

Copolymerization of methyl vinyl ketone with styrene in the presence of cobalt(II) nitrate

1991 ◽  
Vol 47 (1) ◽  
pp. 329-336 ◽  
Author(s):  
Seizo Masuda ◽  
Keiji Minagawa ◽  
Masami Tanaka ◽  
Yutaka Asahi
Keyword(s):  
Vinyl Ketone ◽  
Methyl Vinyl Ketone ◽  
Methyl Vinyl

Additional conformer observed in the microwave spectrum of methyl vinyl ketone

2011 ◽  
Vol 508 (1-3) ◽  
pp. 10-16 ◽  
Author(s):  
David S. Wilcox ◽  
Amanda J. Shirar ◽  
Owen L. Williams ◽  
Brian C. Dian
Keyword(s):  
Microwave Spectrum ◽  
Vinyl Ketone ◽  
Methyl Vinyl Ketone ◽  
Methyl Vinyl
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