The Transfer of Oxygen Atoms in Oxidation—Reduction Reactions. III. The Reaction of Halogenates with Sulfite in Aqueous Solution

1952 ◽  
Vol 74 (2) ◽  
pp. 375-380 ◽  
Author(s):  
Joseph Halperin ◽  
Henry Taube
Keyword(s):  
Aqueous Solution ◽  
Reduction Reactions ◽  
Oxidation Reduction ◽  
Oxygen Atoms

Propriétés de solvation des solutions concentrées en acide phosphorique

1986 ◽  
Vol 64 (3) ◽  
pp. 608-614 ◽  
Author(s):  
C. Louis ◽  
J. Bessière
Keyword(s):  
Activity Coefficients ◽  
Acid Solutions ◽  
Reduction Reactions ◽  
Basic Properties ◽  
Transfer Activity ◽  
Oxidation Reduction ◽  
Normal Potential ◽  
Oxygen Atoms

Solvation properties of ions inH2O–H3PO4 media (1–14 M) are characterized with their solvation transfer activity coefficients f. These are calculated from normal potential or solubility values, and indicate an increasing solvation for anions and decreasing solvation for cations in concentrated acid solutions. For each species, the range depends on its number of charges, on the existence of oxygen atoms in its structure, and on its basic properties. The consequences of variation of solvation on oxidation–reduction reactions and solubility properties are studied.

Mechanisms of some oxidation-reduction reactions between metal cations in aqueous solution

1960 ◽  
Vol 29 ◽  
pp. 49 ◽  
Author(s):  
W. C. E. Higginson ◽  
D. R. Rosseinsky ◽  
J. B. Stead ◽  
A. G. Sykes
Keyword(s):  
Aqueous Solution ◽  
Metal Cations ◽  
Reduction Reactions ◽  
Oxidation Reduction

Feedback Controlled Chemical Reactor with Feed of Two Reaction Components with Spectrophotometric Indication

1994 ◽  
Vol 59 (3) ◽  
pp. 549-557
Author(s):  
František Skopal ◽  
Václav Dušek
Keyword(s):  
Sulfuric Acid ◽  
Negative Feedback ◽  
Chemical Reactor ◽  
Reduction Reactions ◽  
Oxidation Reduction

Theoretical relationships and simplifying conditions have been derived for the feed of two reaction components into a nonisochoric reactor with ideal stirring. The feed of reaction components is controlled by the negative feedback at a constant absorbance of the reaction mixture. The theoretical relationships have been verified using model 2. order oxidation-reduction reactions of Ce(IV)/V(IV) and Fe(III)/V(III) in 1 M sulfuric acid at 20 °C.

Volumetric studies in oxidation-reduction reactions

1958 ◽  
Vol 19 ◽  
pp. 10-11 ◽  
Author(s):  
Balwant Singh ◽  
Sardul Singh
Keyword(s):  
Reduction Reactions ◽  
Oxidation Reduction
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