The Thermodynamics of the Thermal Decomposition of Acetic Acid in the Vapor Phase

1964 ◽  
Vol 86 (2) ◽  
pp. 182-187 ◽  
Author(s):  
William C. Child ◽  
Arthur J. Hay
1972 ◽  
Vol 25 (10) ◽  
pp. 2107 ◽  
Author(s):  
GB Deacon ◽  
GD Fallon

Bismuth triarenesulphinates, Bi(02SR)3 [R = Ph, p-MeC6H4, p-ClC6H4, 2,4,6-(Me2CH)3C6H2, and p-MeCONHC6H4], have been prepared by reaction of bismuth triacetate with the appropriate arenesulphinio acids in glacial acetic acid, and the first two compounds have also been obtained by reaction of triphenyl-bismuth with the appropriate mercuric arenesulphinates. The sulphur-oxygen stretching frequencies of the bismuth sulphinates are indicative of O-sulphinate coordination, and the compounds are considered to be polymeric with bridging O-sulphinate groups and six-coordinate bismuth. Thermal decomposition of Bi(O2SR)3 (R = Ph, p-MeC6H4, or p-CIC6H4) under vacuum gave the corresponding triarylbismuth compounds and sulphur dioxide, the preparation of tri-p-chlorophenylbismuth being accompanied by formation of di-p-chlorophenyl sulphone and S-p-chlorophenyl p-chlorobenzenethiosulphonate. Pyrolysis of the other triarenesulphinates did not yield organobismuth compounds.


2021 ◽  
Vol 285 ◽  
pp. 119826
Author(s):  
S. Gutiérrez-Rubio ◽  
M. Shamzhy ◽  
J. Čejka ◽  
D.P. Serrano ◽  
I. Moreno ◽  
...  
Keyword(s):  

2001 ◽  
Vol 40 (1) ◽  
pp. 101-107 ◽  
Author(s):  
J. Michael Davidson ◽  
Caroline M. McGregor (née Shirrida ◽  
L. K. Doraiswamy

RSC Advances ◽  
2016 ◽  
Vol 6 (40) ◽  
pp. 33332-33338 ◽  
Author(s):  
Li Kang ◽  
Zhixian Wei ◽  
Jiangfeng Song ◽  
Yuanyuan Qu ◽  
Yale Wang

The DSC curves of the AP thermal decomposition in the absence and presence of compounds 1, 2 or their mixtures.


1969 ◽  
Vol 72 (9) ◽  
pp. 1945-1948 ◽  
Author(s):  
Yuichi MURAKAMI ◽  
Tatsuhiko HATTORI ◽  
Hiroshi UCHIDA

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