Stereospecific Alkane Hydroxylation by Non-Heme Iron Catalysts:  Mechanistic Evidence for an FeVO Active Species

2001 ◽  
Vol 123 (26) ◽  
pp. 6327-6337 ◽  
Author(s):  
Kui Chen ◽  
Lawrence Que
Keyword(s):  
Active Species ◽  
Heme Iron ◽  
Iron Catalysts ◽  
Non Heme Iron ◽  
Alkane Hydroxylation

Biologically inspired non-heme iron-catalysts for asymmetric epoxidation; design principles and perspectives

2015 ◽  
Vol 51 (76) ◽  
pp. 14285-14298 ◽  
Author(s):  
Olaf Cussó ◽  
Xavi Ribas ◽  
Miquel Costas
Keyword(s):  
Design Principles ◽  
Heme Iron ◽  
Asymmetric Epoxidation ◽  
Iron Catalysts ◽  
Biologically Inspired ◽  
Feature Article ◽  
Non Heme Iron

This feature article collects the progress in the development of non-heme iron catalysts for asymmetric epoxidation.

A non-heme cationic Fe(iii)-complex intercalated in montmorillonite K-10: synthesis, characterization and catalytic alkane hydroxylation with H2O2 at room temperature

2014 ◽  
Vol 4 (9) ◽  
pp. 3180-3185 ◽  
Author(s):  
Anand Pariyar ◽  
Suranjana Bose ◽  
Achintesh Narayan Biswas ◽  
Sudip Barman ◽  
Pinaki Bandyopadhyay
Keyword(s):  
Room Temperature ◽  
Heme Iron ◽  
Environmentally Benign ◽  
Efficient Catalyst ◽  
Non Heme Iron ◽  
Alkane Hydroxylation ◽  
Selective Hydroxylation

An efficient catalyst for highly selective hydroxylation of alkanes with environmentally benign H2O2 at room temperature has been designed by the intercalation of a non-heme iron(iii) complex into smectite montmorillonite K-10.

Olefin Cis-Dihydroxylation versus Epoxidation by Non-Heme Iron Catalysts:  Two Faces of an FeIII−OOH Coin

2002 ◽  
Vol 124 (12) ◽  
pp. 3026-3035 ◽  
Author(s):  
Kui Chen ◽  
Miquel Costas ◽  
Jinheung Kim ◽  
Adrianne K. Tipton ◽  
Lawrence Que
Keyword(s):  
Heme Iron ◽  
Iron Catalysts ◽  
Non Heme Iron
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