Boric acid esters. I. General survey of aromatic ligands and the kinetics and mechanism of the formation and hydrolysis of boric acid esters of salicylamide, N-phenylsalicylamide, and disalicylimide

1967 ◽  
Vol 89 (26) ◽  
pp. 6954-6971 ◽  
Author(s):  
Donald W. Tanner ◽  
Thomas C. Bruice
Keyword(s):  
Boric Acid ◽  
Kinetics And Mechanism ◽  
General Survey ◽  
Hydrolysis Of ◽  
Acid Esters

Preparation and Rate of Hydrolysis of Boric Acid Esters

1957 ◽  
Vol 49 (2) ◽  
pp. 174-181 ◽  
Author(s):  
Howard Steinberg ◽  
D. L. Hunter
Keyword(s):  
Boric Acid ◽  
Rate Of Hydrolysis ◽  
Hydrolysis Of ◽  
Acid Esters

Die Hydrolyse einiger Borsäureester unter Base-Einfluß in nichtwäßrigen Lösungsmitteln / The Hydrolysis of Some Tris(organyloxy)boranes under Alkaline Influence in Non-aqueous Solvents

1976 ◽  
Vol 31 (6) ◽  
pp. 714-720 ◽  
Author(s):  
G. Heller ◽  
H. Ross
Keyword(s):  
Boric Acid ◽  
Organic Solvents ◽  
Mother Liquor ◽  
Acid Ester ◽  
Reaction Medium ◽  
Ester Hydrolysis ◽  
Boric Acid Ester ◽  
Hydrolysis Of ◽  
Acid Esters

The hydrolysis of tris(organyloxy)boranes (boric acid esters) in organic solvents in the presence of KOH leading to potassium polyborates (free from water of crystallization) is studied as to the influences of (a) the reaction medium (ethanol or ligroine/ethanol), (b) the concentration of water, (c) the organyl group of the boric acid ester (methyl, isopropyl, or phenyl), (d) the time of stay of the precipitated insoluble polyborates under the mother liquor (15 to 61850 s), and (e) the temperature during precipitation and the time of stay (—18 to + 60°C).In the first stage of the reaction, during precipitation time, ester hydrolysis is followed by condensation, while aggregation and desorption processes occur between the time of precipitation and filtration.

ChemInform Abstract: KINETICS AND MECHANISM OF THE HYDROLYSIS OF IMIDOYL HALIDES

1976 ◽  
Vol 7 (40) ◽  
pp. no-no
Author(s):  
TAE-RIN KIM ◽  
JIN-HEE KIM ◽  
BYUNG-DOO CHANG ◽  
KWANG-IL LEE ◽  
UNG-CHO KIM
Keyword(s):  
Kinetics And Mechanism ◽  
Hydrolysis Of
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