Insertion reactions of nortricyclene with ethyl diazoacetate

1967 ◽  
Vol 89 (18) ◽  
pp. 4695-4698 ◽  
Author(s):  
Ronald R. Sauers ◽  
Robert J. Kiesel
Keyword(s):  
Insertion Reactions ◽  
Ethyl Diazoacetate

Iron Porphyrin Catalyzed N−H Insertion Reactions with Ethyl Diazoacetate

2007 ◽  
Vol 26 (16) ◽  
pp. 3995-4002 ◽  
Author(s):  
Lynnette K. Baumann ◽  
Harun M. Mbuvi ◽  
Guodong Du ◽  
L. Keith Woo
Keyword(s):  
Iron Porphyrin ◽  
Insertion Reactions ◽  
Ethyl Diazoacetate

[OsH4(PPh3)3]: New Catalyst for the Selective Cyclopropanation of Activated Olefins

1996 ◽  
Vol 61 (12) ◽  
pp. 1798-1804 ◽  
Author(s):  
Albert Demonceau ◽  
François Simal ◽  
Corine A. Lemoine ◽  
Alfred F. Noels ◽  
Igor T. Chizhevsky ◽  
...  
Keyword(s):  
Title Compound ◽  
Efficient Catalyst ◽  
Ethyl Diazoacetate ◽  
Styrene Derivatives ◽  
Activated Olefins ◽  
Cyclic Alkenes

The title compound was found to be an efficient catalyst for the selective cyclopropanation of activated olefins by ethyl diazoacetate. The cyclopropane yields range from moderate to good (75 to 95%) for activated olefins such as styrene and styrene derivatives, but are rather low (20 to 30%) for non-activated olefins such as terminal and cyclic alkenes. In the intermolecular competition, styrene was 45 times more reactive than cyclooctene. In all cases, trans (exo) cyclopropane predominated over the cis (endo) isomer.

Synthetic Scope of Brønsted Acid-Catalyzed Reactions of Carbonyl Compounds and Ethyl Diazoacetate

2021 ◽  
Author(s):  
Mizzanoor Rahaman ◽  
M. Shahnawaz Ali ◽  
Khorshada Jahan ◽  
Damon Hinz ◽  
Jawad Bin Belayet ◽  
...  
Keyword(s):  
Carbonyl Compounds ◽  
Bronsted Acid ◽  
Brønsted Acid ◽  
Ethyl Diazoacetate ◽  
Brönsted Acid ◽  
Acid Catalyzed ◽  
Catalyzed Reactions

scholarly journals Reply to “Comment on ‘Atomistic Mechanisms of Mg Insertion Reactions in Group XIV Anodes for Mg-Ion Batteries’”

2020 ◽  
Vol 12 (13) ◽  
pp. 14739-14740
Author(s):  
Mingchao Wang ◽  
Jodie A. Yuwono ◽  
Vallabh Vasudevan ◽  
Nick Birbilis ◽  
Nikhil V. Medhekar
Keyword(s):  
Insertion Reactions ◽  
Group Xiv

The chemistry of stabilized clusters

1982 ◽  
Vol 308 (1501) ◽  
pp. 27-34 ◽  
Keyword(s):  
Electron Donor ◽  
Organic Molecules ◽  
Metal Cluster ◽  
Organic Substrates ◽  
Insertion Reactions ◽  
Donor Ligand ◽  
Small Organic Molecules ◽  
Wide Range ◽  
Metal Metal ◽  
High Yields

Studies of the chemistry of metal cluster complexes and, in particular, their reactions with small organic molecules, have been confined to relatively few systems. Among the reasons for this are: (i) not many clusters are easily synthesized in high yields; (ii) their reactions often give a multitude of products that are difficult to separate and characterize; (iii) the conditions required to bring about reactions often lead to fragmentation of the cluster into lower nuclearity (often mononuclear) species. One cluster whose chemistry has been extensively studied is [Os 3 H 2 (CO) 10 ]. This can be synthesized in high yields from [Os 3 (CO) 12 ] + H 2 (Knox et al. 1975) and reacts readily under mild conditions with a wide range of electron-donor molecules by virtue of its coordinative unsaturation (Shapley et al. 1975; Deeming & Hasso 1976; Adams & Golembeski 1979). Formally, one may consider that a metal—metal double bond is present, which is reduced to a single bond on coordination of an additional two-electron donor ligand such as an organophosphine. The presence of metal—hydrogen bonds in this cluster and the cluster’s ability to coordinate organic substrates enable it to undergo a wide variety of insertion reactions, leading to products that may be regarded as intermediates in the reduction of organic molecules by clusters (Deeming & Hasso 1975; Keister & Shapley 1975).

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