Nickel Carbonyl Complexes with Bifunctional Nonchelate Ligands1

1966 ◽  
Vol 88 (22) ◽  
pp. 5354-5355 ◽  
Author(s):  
Anton B. Burg ◽  
Robert A. Sinclair
Keyword(s):  
Carbonyl Complexes ◽  
Nickel Carbonyl

Alkali Metal Covalent Bonding in Nickel Carbonyl Complexes ENi(CO) 3 −

2019 ◽  
Vol 131 (6) ◽  
pp. 1746-1752 ◽  
Author(s):  
Chaoxian Chi ◽  
Sudip Pan ◽  
Luyan Meng ◽  
Mingbiao Luo ◽  
Lili Zhao ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Covalent Bonding ◽  
Carbonyl Complexes ◽  
Nickel Carbonyl

Facile Syntheses of Silylene Nickel Carbonyl Complexes from Lewis Base Stabilized Chlorosilylenes†

2010 ◽  
Vol 49 (21) ◽  
pp. 10199-10202 ◽  
Author(s):  
Gašper Tavčar ◽  
Sakya S. Sen ◽  
Ramachandran Azhakar ◽  
Andrea Thorn ◽  
Herbert W. Roesky
Keyword(s):  
Lewis Base ◽  
Carbonyl Complexes ◽  
Nickel Carbonyl

scholarly journals Synthesis, Structure and Nickel Carbonyl Complexes of Dialkylterphenyl Phosphines

2018 ◽  
Vol 25 (1) ◽  
pp. 260-272 ◽  
Author(s):  
Mario Marín ◽  
Juan J. Moreno ◽  
Carlos Navarro‐Gilabert ◽  
Eleuterio Álvarez ◽  
Celia Maya ◽  
...  
Keyword(s):  
Carbonyl Complexes ◽  
Nickel Carbonyl

Reactions of Ni(CO) 3 and the heterogeneous oxidation of Ni(CO) 4 and Fe(CO) 5

1961 ◽  
Vol 265 (1320) ◽  
pp. 88-96 ◽  
Keyword(s):  
Room Temperature ◽  
Colloidal Particles ◽  
Flash Photolysis ◽  
Heterogeneous Reaction ◽  
Metal Carbonyl ◽  
Iron Pentacarbonyl ◽  
Carbonyl Complexes ◽  
Heterogeneous Oxidation ◽  
Nickel Carbonyl ◽  
Gaseous Products

It is shown that the oxidation of metal carbonyl complexes can be studied by flash photolysis and kinetic spectroscopy. Reaction was initiated in mixtures of nickel carbonyl, carbon monoxide and oxygen by flash photolysis; from the effect of total pressure on the decomposition, it was concluded that Ni(CO) 3 reacts with oxygen without a third-body requirement, the collision efficiency being about 1·5 x 10·3. A slow reaction continued after the flash, due to the heterogeneous grow th of the colloidal particles produced during the flash. A heterogeneous reaction of nickel carbonyl and iron pentacarbonyl with oxygen at room temperature was described. Analysis of the gaseous products gave the following equations of nearest stoichiometry: Ni(CO) 4 + O 2 → Ni(CO)O + CO 2 + 2CO, 2Fe(CO) 5 + 3O 2 → Fe 2 O 2 (CO) + 5CO + 4CO 2 . These carbonyl oxides belong to a new class of chemical substances. They are stable at room temperature but lose CO on heating in a vacuum .

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