Proton Magnetic Resonance Studies of Metal Complexes of Imidazole, Purine, and Pyrimidine Derivatives1

1966 ◽  
Vol 88 (20) ◽  
pp. 4592-4597 ◽  
Author(s):  
Sung Mao Wang ◽  
Norman C. Li
1972 ◽  
Vol 27 (9) ◽  
pp. 1047-1049 ◽  
Author(s):  
J. Lauterwein ◽  
P. Hemmerich ◽  
J.-M. Lhoste

A detailed magnetic resonance investigation of the metal ion interaction with flavoquinones has been carried out with the purpose of obtaining the stoichiometry, stability and (sub) molecular structure of the complexes. The isotropic shifts of the paramagnetic chelates are analysed in terms of contact and pseudocontact contribution. It is shown that the flavoquinone-metal binding is mainly of σ-type regardless of the nature of the ion.


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