Phosphonic Acid Analogs of Nucleoside Phosphates. I. The Synthesis of 5″-Adenylyl Methylenediphosphonate, a Phosphonic Acid Analog of ATP

1963 ◽  
Vol 85 (20) ◽  
pp. 3292-3295 ◽  
Author(s):  
Terrell C. Myers ◽  
Kaname. Nakamura ◽  
James W. Flesher
Keyword(s):  
Phosphonic Acid ◽  
Acid Analog

Synthesis of the Phosphonic Acid Analog of Serine

Synthesis ◽  
1984 ◽  
Vol 1984 (07) ◽  
pp. 577-580 ◽  
Author(s):  
Barbara Lejczak ◽  
Paweł Kafarski ◽  
Mirosław Soroka ◽  
Przemysław Mastalerz
Keyword(s):  
Phosphonic Acid ◽  
Acid Analog

Phosphonic Acid Analogs of Carbohydrate Metabolites. IV. Synthesis of DL-Glyceraldehyde-3-phosphonic Acid

1973 ◽  
Vol 51 (1) ◽  
pp. 104-110 ◽  
Author(s):  
Erich Baer ◽  
Ranga Robinson
Keyword(s):  
Phosphoric Acid ◽  
Chemical Synthesis ◽  
Phosphonic Acid ◽  
Methylphosphonic Acid ◽  
Diethyl Ester ◽  
Acid Analog ◽  
Protective Groups ◽  
Carbohydrate Metabolites

A chemical synthesis of DL-glyceraldehyde-3-phosphonic acid, the phosphonic acid analog of DL-glyceraldehyde-3-phosphoric acid, is reported. It was obtained from dimer DL-glyceraldehyde by two procedures differing solely in their protective groups via the following intermediates. Procedure 1: 2,5-diiodomethyl-3,6-dimethoxy-1,4-dioxane → 2,5-bis(methylphosphonic acid diethyl ester)-3,6-dimethoxy-1,4-dioxane → 2,5-bis(methylphosphonic acid)-3,6-dimethoxy-1,4-dioxane → DL-glyceraldehyde-3-phosphonic acid. Procedure 2: 2,5-bis(p-toluenesulfonyloxymethyl)-3,6-dibenzoxy-l,4-dioxane → 2,5-diiodomethyl-3,6-dibenzoxy-l,4-dioxane → 2,5-bis(methylphosphonic acid diethyl ester)-3,6-dibenzoxy-l,4-dioxane → 2,5-bis(methylphosphonicacid)-3,6-dibenzoxy-1,4-dioxane → DL-glyceraldehyde-3-phosphonic acid.

An Improved Synthesis of the Phosphonic Acid Analog of Tryptophan

Synlett ◽  
1992 ◽  
Vol 1992 (09) ◽  
pp. 708-708 ◽  
Author(s):  
Roland S. Rogers ◽  
Michael K. Stern
Keyword(s):  
Phosphonic Acid ◽  
Acid Analog

ChemInform Abstract: An Improved Synthesis of the Phosphonic Acid Analog of Tryptophan.

ChemInform ◽  
2010 ◽  
Vol 24 (22) ◽  
pp. no-no
Author(s):  
R. S. ROGERS ◽  
M. K. STERN
Keyword(s):  
Phosphonic Acid ◽  
Acid Analog
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