Ionization Rates of Weak Acids. I. Base-Catalyzed Proton Exchange between Toluene and Tritiated Dimethyl Sulfoxide

1963 ◽  
Vol 85 (19) ◽  
pp. 3000-3002 ◽  
Author(s):  
J. E. Hofmann ◽  
Rene J. Muller ◽  
A. Schriesheim
Keyword(s):  
Dimethyl Sulfoxide ◽  
Proton Exchange ◽  
Weak Acids ◽  
Ionization Rates

Hydrocarbon-Carbanion Proton Exchange Reactions in Dimethyl Sulfoxide

1967 ◽  
Vol 89 (7) ◽  
pp. 1728-1730 ◽  
Author(s):  
John I. Brauman ◽  
Donald F. McMillen ◽  
Yoko. Kanazawa
Keyword(s):  
Dimethyl Sulfoxide ◽  
Proton Exchange ◽  
Exchange Reactions

The Acidities of Weak Acids in Dimethyl Sulfoxide

1963 ◽  
Vol 85 (19) ◽  
pp. 3054-3055 ◽  
Author(s):  
Edwin C. Steiner ◽  
Joanne M. Gilbert
Keyword(s):  
Dimethyl Sulfoxide ◽  
Weak Acids

The Rate of Ionization of Some Aromatic Hydrocarbons in Ethanolic Dimethyl Sulfoxide

1974 ◽  
Vol 52 (7) ◽  
pp. 1059-1061 ◽  
Author(s):  
A. Albagli ◽  
J. R. Jones ◽  
Ross Stewart
Keyword(s):  
Dimethyl Sulfoxide ◽  
Aromatic Hydrocarbons ◽  
Sodium Ethoxide ◽  
Ionization Rate ◽  
Unit Slope ◽  
Straight Line ◽  
Ionization Rates

The rates of detritiation of triphenlymethane, 9-phenylxanthene, fluorene, 9-ethylfluorene, 9-phenylfiuorene, and 2,3-benzofluorene have been measured in ethanolic dimethyl sulfoxide (DMSO) containing sodium ethoxide. When the logarithm of the ionization rate is plotted against the logarithm of the ionization rate of DMSO a straight line of near-to-unit slope is obtained in each case. There are significant differences, however, between relative ionization rates and equilibrium acidities.

Rates of Proton Exchange between Dimethyl Sulfoxide and Its Conjugate Base

1966 ◽  
Vol 88 (10) ◽  
pp. 2332-2334 ◽  
Author(s):  
John I. Brauman ◽  
Norvelle J. Nelson
Keyword(s):  
Dimethyl Sulfoxide ◽  
Proton Exchange ◽  
Conjugate Base
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