The Reaction of Sodium Borohydride with Nickel Acetate in Ethanol Solution--A Highly Selective Nickel Hydrogenation Catalyst

1963 ◽  
Vol 85 (7) ◽  
pp. 1005-1006 ◽  
Author(s):  
Herbert C. Brown ◽  
Charles A. Brown
Keyword(s):  
Sodium Borohydride ◽  
Ethanol Solution ◽  
Nickel Acetate ◽  
Hydrogenation Catalyst

A Modified Method to Prepare Diselenides by the Reaction of Selenium with Sodium Borohydride

2002 ◽  
Vol 2002 (4) ◽  
pp. 160-161 ◽  
Author(s):  
Xiangliang Yang ◽  
Qin Wang ◽  
Yunhai Tao ◽  
Huibi Xu
Keyword(s):  
Sodium Borohydride ◽  
Ethanol Solution ◽  
Molar Ratio ◽  
Modified Method ◽  
High Yields

With a 8:1 molar ratio of selenium to borohydride, sodium diselenide can be prepared conveniently and safely in alkaline aqueous or ethanol solution, which can be used directly to synthesise symmetric diselenides in high yields.

TEM study of order, structure and defects of β and martensite in Cu-Al-Mn shape memory alloys

1990 ◽  
Vol 48 (4) ◽  
pp. 188-189
Author(s):  
J.M. Guilemany ◽  
F. Peregrin
Keyword(s):  
Shape Memory ◽  
Orthophosphoric Acid ◽  
Isopropyl Alcohol ◽  
Metastable Phase ◽  
Characteristic Temperature ◽  
Ethanol Solution ◽  
Order Structure ◽  
Thin Foils ◽  
Polycrystalline Alloys ◽  
Diamond Saw

The shape memory effect (SME) shown by Cu-Al-Mn alloys stems from the thermoelastic martensitic transformation occuring between a β (L2,) metastable phase and a martensitic phase. The TEM study of both phases in single and polycrystalline Cu-Al-Mn alloys give us greater knowledge of the structure, order and defects.The alloys were obtained by vacuum melting of Cu, Al and Mn and single crystals were obtained from polycrystalline alloys using a modified Bridgman method. Four different alloys were used with (e/a) ranging from 1.41 to 1.46 . Two different heat treatments were used and the alloys also underwent thermal cycling throughout their characteristic temperature range -Ms, Mf, As, Af-. The specimens were cut using a low speed diamond saw and discs were mechanically thinned to 100 μm and then ion milled to perforation at 4 kV. Some thin foils were also prepared by twin-jet electropolishing, using a (1:10:50:50) urea: isopropyl alcohol: orthophosphoric acid: ethanol solution at 20°C. The foils were examinated on a TEM operated at 200 kV.

Polysulfide-borohydride modification of southern pine alkaline pulping integrated with hydrothermal pre-extraction of hemicelluloses

TAPPI Journal ◽  
2011 ◽  
Vol 10 (7) ◽  
pp. 9-16
Author(s):  
SUNG-HOON YOON ◽  
HARRY CULLINAN ◽  
GOPAL A. KRISHNAGOPALAN
Keyword(s):  
Loblolly Pine ◽  
Sodium Borohydride ◽  
Kraft Pulping ◽  
Hot Water ◽  
Pulp Yield ◽  
Paper Strength ◽  
Southern Pine ◽  
Two Stage ◽  
Simultaneous Treatment ◽  
Process Modification

We studied three process modifications to investigate their effects on the property and yield recovery capabilities of kraft pulping integrated with hemicellulose pre-extraction of southern pine. Loblolly pine chips were pre-extracted with hot water until the sugar extraction yield reached the targeted value of 10% and then subjected to conventional and modified kraft pulping. Modification included polysulfide pretreatment; polysulfide-sodium borohydride dual pretreatment, and polysulfide followed by polysulfide-sodium borohydride dual pretreatment two-stage pretreatments prior to kraft pulping. In the first modification, about 5% of the lost pulp yield (total 7%) caused by hemicellulose pre-extraction could be recovered with 15%-20% polysulfide pretreatment. Complete recovery (7%) was achieved with simultaneous pretreatment using 15% polysulfide and 0.5% sodium borohydride with 0.1% anthraquinone in polysulfide-sodium borohydride dual pretreatment. Two-stage pretreatment using recycled 15% polysulfide followed by simultaneous treatment of 6% polysulfide and 0.4%–0.5% sodium borohydride with 0.1% anthraquinone also achieved 100% yield recovery. Continuous recycling of 15% polysulfide employed in the two-stage process modification maintained its yield protection efficiency in a repeated recycling cycle. No significant changes in paper strength were found in handsheets prepared from the three process modifications, except for a minor reduction in tear strength.

Induced Consumption of High-Concentration Ethanol Solution in Rats

1969 ◽  
Vol 30 (2) ◽  
pp. 330-335 ◽  
Author(s):  
R. J. Senter ◽  
Charles L. Richman
Keyword(s):  
Ethanol Solution ◽  
High Concentration

Synthesis and Characterization of Silver Nanoplates by a Seed-mediated Method

2019 ◽  
Vol 29 (3) ◽  
Author(s):  
Mai Ngọc Tuan Anh
Keyword(s):  
Hydrogen Peroxide ◽  
Silver Nanoparticles ◽  
Ascorbic Acid ◽  
Silver Nitrate ◽  
Sodium Borohydride ◽  
Trisodium Citrate ◽  
Synthesis And Characterization ◽  
Silver Nanoplates ◽  
Seed Mediated

Silver nanoplates (SNPs) having different size were synthesized by a seed-mediated method. The seeds -silver nanoparticles with 4 – 6 nm diameters were synthesized first by reducing silver nitrate with sodium borohydride in the present of Trisodium Citrate and Hydrogen peroxide. Then these seeds were developed by continue reducing Ag\(^+\) ions with various amount of L-Ascorbic acid to form SNPs. Our analysis showed that the concentratrion of L-Ascorbic acid, a secondary reducing agent, played an important role to form SNPs. In addition, the size and in-plane dipole plasmon resonance wavelenght of silver nanoplates were increased when the concentration of added silver nitrate increased. The characterization of SNPs were studied by UV-Vis, FE-SEM, EDS and TEM methods.

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