Mechanistic photochemistry of .gamma.,.delta.-unsaturated ketones. Discovery of a photo-Cope reaction of .beta.-oxa-.gamma..delta.-enones and its implications for the mechanisms of intramolecular photocycloaddition

J. Christopher Dalton; Samuel J. Tremont

doi:10.1021/ja00856a078

Mechanistic photochemistry of .gamma.,.delta.-unsaturated ketones. Discovery of a photo-Cope reaction of .beta.-oxa-.gamma..delta.-enones and its implications for the mechanisms of intramolecular photocycloaddition

Journal of the American Chemical Society ◽

10.1021/ja00856a078 ◽

1975 ◽

Vol 97 (23) ◽

pp. 6916-6917 ◽

Cited By ~ 14

Author(s):

J. Christopher Dalton ◽

Samuel J. Tremont

Keyword(s):

Gamma Delta ◽

Unsaturated Ketones

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Formation of sulfonium tetrafluoroborates from reactions of .gamma.,.delta.-unsaturated ketones with thiols in the presence of boron trifluoride etherate

The Journal of Organic Chemistry ◽

10.1021/jo00356a013 ◽

1986 ◽

Vol 51 (6) ◽

pp. 825-829 ◽

Cited By ~ 7

Author(s):

Alan P. Marchand ◽

Riza Kaya ◽

Steven W. Muchmore ◽

Dick Van der Helm

Keyword(s):

Boron Trifluoride ◽

Boron Trifluoride Etherate ◽

Gamma Delta ◽

Unsaturated Ketones

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Organic synthesis using haloboration reaction. Part 7. A stereospecific synthesis of (Z)-.delta.-halo-.gamma.,.delta.-unsaturated ketones via haloboration reaction of terminal alkynes

Journal of the American Chemical Society ◽

10.1021/ja00304a032 ◽

1985 ◽

Vol 107 (18) ◽

pp. 5225-5228 ◽

Cited By ~ 30

Author(s):

Yoshitaka Satoh ◽

Hirokazu Serizawa ◽

Shoji Hara ◽

Akira Suzuki

Keyword(s):

Organic Synthesis ◽

Stereospecific Synthesis ◽

Terminal Alkynes ◽

Gamma Delta ◽

Unsaturated Ketones

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Organic photochemistry with 6.7-eV photons: .gamma.,.delta.-unsaturated ketones

Journal of the American Chemical Society ◽

10.1021/ja00380a017 ◽

1982 ◽

Vol 104 (16) ◽

pp. 4424-4429 ◽

Cited By ~ 11

Author(s):

William J. Leigh ◽

R. Srinivasan

Keyword(s):

Gamma Delta ◽

Unsaturated Ketones ◽

Organic Photochemistry

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Alkylation-reduction of carbonyl systems. 10. Regiospecific synthesis of 1,4-dienes by alkylation-reduction of .alpha.,.beta.,.gamma.,.delta.-unsaturated ketones

The Journal of Organic Chemistry ◽

10.1021/jo01321a029 ◽

1979 ◽

Vol 44 (7) ◽

pp. 1159-1161 ◽

Cited By ~ 7

Author(s):

Judith S. Ryan Zilenovski ◽

Stan S. Hall

Keyword(s):

Gamma Delta ◽

Unsaturated Ketones ◽

Alpha Beta

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ChemInform Abstract: MECHANISTIC STUDIES ON THE PHOTOCYCLIZATION OF GAMMA,DELTA-UNSATURATED KETONES

Chemischer Informationsdienst ◽

10.1002/chin.197544114 ◽

1975 ◽

Vol 6 (44) ◽

pp. no-no

Author(s):

RONALD R. SAUERS ◽

ALAN D. ROUSSEAU ◽

BRIAN BYRNE

Keyword(s):

Mechanistic Studies ◽

Gamma Delta ◽

Unsaturated Ketones

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Ruthenium-catalyzed addition of allyl alcohols and acetylenes. A simple synthesis of .gamma.,.delta.-unsaturated ketones

Journal of the American Chemical Society ◽

10.1021/ja00075a083 ◽

1993 ◽

Vol 115 (22) ◽

pp. 10402-10403 ◽

Cited By ~ 59

Author(s):

Barry M. Trost ◽

Jose A. Martinez ◽

Robert J. Kulawiec ◽

Adriano F. Indolese

Keyword(s):

Simple Synthesis ◽

Gamma Delta ◽

Unsaturated Ketones ◽

Allyl Alcohols

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A new method for the preparation of .gamma.,.delta.-unsaturated ketones via Claisen rearrangement

The Journal of Organic Chemistry ◽

10.1021/jo00223a056 ◽

1985 ◽

Vol 50 (23) ◽

pp. 4664-4665 ◽

Cited By ~ 23

Author(s):

George Buchi ◽

Dennis E. Vogel

Keyword(s):

Claisen Rearrangement ◽

New Method ◽

Gamma Delta ◽

Unsaturated Ketones

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Selective synthesis of complex aromatic alkenes. (1,4-Cyclohexadienyl)alkenes by tandem arylation-multistep reduction of .alpha.,.beta.,.gamma.,.delta.-unsaturated ketones

The Journal of Organic Chemistry ◽

10.1021/jo00334a006 ◽

1981 ◽

Vol 46 (21) ◽

pp. 4139-4142 ◽

Cited By ~ 10

Author(s):

Judith S. Ryan Zilenovski ◽

Stan S. Hall

Keyword(s):

Selective Synthesis ◽

Gamma Delta ◽

Unsaturated Ketones ◽

Alpha Beta

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Coupling reactions of vinylmagnesium bromide with imidoyl chlorides and with amides. Synthesis of enol imines, .gamma.,.delta.-unsaturated ketones and ketimines

The Journal of Organic Chemistry ◽

10.1021/jo00318a045 ◽

1981 ◽

Vol 46 (5) ◽

pp. 1039-1041 ◽

Cited By ~ 6

Author(s):

Kai S. Ng ◽

Howard Alper

Keyword(s):

Coupling Reactions ◽

Gamma Delta ◽

Unsaturated Ketones ◽

Imidoyl Chlorides

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Conjugate addition of B-alkenyl-9-borabicyclo[3.3.1]nonanes to methyl vinyl ketone. A convenient synthesis of .gamma.,.delta.-unsaturated ketones

Journal of the American Chemical Society ◽

10.1021/ja00440a069 ◽

1976 ◽

Vol 98 (24) ◽

pp. 7832-7833 ◽

Cited By ~ 51

Author(s):

Peyton Jacob ◽

Herbert Brown

Keyword(s):

Conjugate Addition ◽

Vinyl Ketone ◽

Methyl Vinyl Ketone ◽

Gamma Delta ◽

Methyl Vinyl ◽

Unsaturated Ketones ◽

Convenient Synthesis

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