Composition of lithium aluminum hydride, lithium borohydride, and their alkoxy derivatives in ether solvents as determined by molecular association and conductance studies

E. C. Ashby; Frank R. Dobbs; Harry P. Hopkins

doi:10.1021/ja00844a039

Composition of lithium aluminum hydride, lithium borohydride, and their alkoxy derivatives in ether solvents as determined by molecular association and conductance studies

Journal of the American Chemical Society ◽

10.1021/ja00844a039 ◽

1975 ◽

Vol 97 (11) ◽

pp. 3158-3162 ◽

Cited By ~ 39

Author(s):

E. C. Ashby ◽

Frank R. Dobbs ◽

Harry P. Hopkins

Keyword(s):

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Molecular Association ◽

Lithium Aluminum ◽

Lithium Borohydride ◽

Ether Solvents

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ChemInform Abstract: REDUCTION OF CYCLOHEX-2-ENONE WITH LITHIUM ALUMINUM HYDRIDE AND LITHIUM BOROHYDRIDE- INVERSION OF REGIOSELECTIVITY BY ADDITION OF CRYPTANDS

Chemischer Informationsdienst ◽

10.1002/chin.197841160 ◽

1978 ◽

Vol 9 (41) ◽

Author(s):

A. LOUPY ◽

J. SEYDEN-PENNE

Keyword(s):

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Lithium Aluminum ◽

Lithium Borohydride

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Solubility of lithium aluminum hydride and lithium borohydride in diethyl ether

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science ◽

10.1007/bf00853610 ◽

1971 ◽

Vol 20 (12) ◽

pp. 2497-2500 ◽

Cited By ~ 4

Author(s):

V. I. Mikheeva ◽

E. A. Troyanovskaya

Keyword(s):

Diethyl Ether ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Lithium Aluminum ◽

Lithium Borohydride

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ChemInform Abstract: COMPARATIVE REDUCTION OF CYCLOPENTENONE AND CYCLOHEXENONE BY LITHIUM ALUMINUM HYDRIDE AND LITHIUM BOROHYDRIDE

Chemischer Informationsdienst ◽

10.1002/chin.197602109 ◽

1976 ◽

Vol 7 (2) ◽

pp. no-no

Author(s):

MARIE-CHRISTINE DI GUARDO ◽

CHRISTIAN ARNAUD ◽

JACQUES DURAND ◽

JEAN HUET

Keyword(s):

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Lithium Aluminum ◽

Lithium Borohydride

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The Heats of Formation of Sodium Borohydride, Lithium Borohydride and Lithium Aluminum Hydride

Journal of the American Chemical Society ◽

10.1021/ja01176a052 ◽

1949 ◽

Vol 71 (8) ◽

pp. 2775-2781 ◽

Cited By ~ 64

Author(s):

William D. Davis ◽

L. S. Mason ◽

G. Stegeman

Keyword(s):

Sodium Borohydride ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Heats Of Formation ◽

Lithium Aluminum ◽

Lithium Borohydride

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PARAFFIN-BASED SOLID FUELS FOR HYBRID PROPULSION FILLED WITH LITHIUM ALUMINUM HYDRIDE: THERMAL, MECHANICAL, AND BALLISTIC CHARACTERIZATION

International Journal of Energetic Materials and Chemical Propulsion ◽

10.1615/intjenergeticmaterialschemprop.2017016259 ◽

2016 ◽

Vol 15 (6) ◽

pp. 501-527

Author(s):

Matteo Boiocchi ◽

Luciano Galfetti ◽

Luca Di Landro

Keyword(s):

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Solid Fuels ◽

Lithium Aluminum ◽

Hybrid Propulsion

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ChemInform Abstract: ASYMMETRIC SYNTHESIS VIA AXIALLY DISSYMMETRIC MOLECULES. 7. SYNTHETIC APPLICATIONS OF THE ENANTIOSELECTIVE REDUCTION BY BINAPHTHOL-MODIFIED LITHIUM ALUMINUM HYDRIDE REAGENTS

Chemischer Informationsdienst ◽

10.1002/chin.198508092 ◽

1985 ◽

Vol 16 (8) ◽

Author(s):

R. NOYORI ◽

I. TOMINO ◽

M. YAMADA ◽

M. NISHIZAWA

Keyword(s):

Asymmetric Synthesis ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Lithium Aluminum ◽

Enantioselective Reduction

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NOW, MHI LITHIUM ALUMINUM HYDRIDE FOR NITROGEN GROUP REDUCTIONS!

Chemical & Engineering News ◽

10.1021/cen-v036n026.p014 ◽

1958 ◽

Vol 36 (26) ◽

pp. 14

Keyword(s):

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Lithium Aluminum

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ChemInform Abstract: ORGANIC SONOCHEMISTRY. ULTRASONIC ACCELERATION OF THE REDUCTION OF SIMPLE AND DEACTIVATED ARYL HALIDES USING LITHIUM ALUMINUM HYDRIDE

Chemischer Informationsdienst ◽

10.1002/chin.198238123 ◽

1982 ◽

Vol 13 (38) ◽

Author(s):

B. H. HAN ◽

P. BOUDJOUK

Keyword(s):

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Aryl Halides ◽

Lithium Aluminum

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The Preparation of Heavy Metal Hydride and Its Catalytic Activity. VII. The Hydrogenation of Various Olefins with a Ferric Chloride-Lithium Aluminum Hydride or a Cobaltous Chloride-Lithium Aluminum Hydride Catalyst

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.38.1279 ◽

1965 ◽

Vol 38 (8) ◽

pp. 1279-1285 ◽

Cited By ~ 19

Author(s):

Yoshinobu Takegami ◽

Toru Ueno ◽

Takao Fujii

Keyword(s):

Heavy Metal ◽

Catalytic Activity ◽

Ferric Chloride ◽

Metal Hydride ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Lithium Aluminum ◽

Cobaltous Chloride

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The Preparation of Specifically Deuterated trans- Cinnamyl Alcohol and trans- Cinnamic Acid

Canadian Journal of Chemistry ◽

10.1139/v73-315 ◽

1973 ◽

Vol 51 (13) ◽

pp. 2102-2104 ◽

Cited By ~ 1

Author(s):

Donald G. Lee ◽

James R. Brownridge

Keyword(s):

Cinnamic Acid ◽

Triple Bond ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Lithium Aluminum ◽

Cinnamyl Alcohol ◽

Partial Reduction ◽

Work Up

The reduction of ethyl phenylpropiolate by lithium aluminum hydride results in partial reduction of the triple bond to give trans-cinnamyl alcohol. If ethyl phenylpropiolate is reduced by LiAlD4 followed by work-up with acetone and H2O the product is the specifically labeled compound, trans-3-phenyl-2-propen-1-ol-1,1,2-d3. If the ester is reduced with LiAlH4 followed by work-up with acetone-d6 and D2O the product is trans-3-phenyl-2-propen-1-ol-O,3-d2. Oxidation of these two products by sodium ruthenate leads to formation of trans-cinnamic acid-α-d and trans-cinnamic acid-β-d, respectively.

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