Kinetics of substitution reactions of .alpha.,.beta.,.gamma.,.delta.-tetra(4-N-methylpyridyl)porphinediaquocobalt(III)

1975 ◽  
Vol 97 (6) ◽  
pp. 1422-1426 ◽  
Author(s):  
Kenneth R. Ashley ◽  
Margot Berggren ◽  
Meirong Cheng
Keyword(s):  
Gamma Delta ◽  
Substitution Reactions ◽  
Alpha Beta ◽  
Kinetics Of

Evidence for general base catalysis by protic solvents in a kinetic study of alcoholyses and hydrolyses of 1-(phenoxycarbonyl)pyridinium ions under both solvolytic and non-solvolytic conditions

2009 ◽  
Vol 74 (1) ◽  
pp. 43-55 ◽  
Author(s):  
Dennis N. Kevill ◽  
Byoung-Chun Park ◽  
Jin Burm Kyong
Keyword(s):  
Second Order ◽  
Base Catalysis ◽  
Substitution Reactions ◽  
Third Order ◽  
Methoxy Derivative ◽  
First Order ◽  
General Base ◽  
Protic Solvents ◽  
Kinetics Of ◽  
Pyridinium Ions

The kinetics of nucleophilic substitution reactions of 1-(phenoxycarbonyl)pyridinium ions, prepared with the essentially non-nucleophilic/non-basic fluoroborate as the counterion, have been studied using up to 1.60 M methanol in acetonitrile as solvent and under solvolytic conditions in 2,2,2-trifluoroethan-1-ol (TFE) and its mixtures with water. Under the non- solvolytic conditions, the parent and three pyridine-ring-substituted derivatives were studied. Both second-order (first-order in methanol) and third-order (second-order in methanol) kinetic contributions were observed. In the solvolysis studies, since solvent ionizing power values were almost constant over the range of aqueous TFE studied, a Grunwald–Winstein equation treatment of the specific rates of solvolysis for the parent and the 4-methoxy derivative could be carried out in terms of variations in solvent nucleophilicity, and an appreciable sensitivity to changes in solvent nucleophilicity was found.

scholarly journals Trigonometric approximation of functions $f(x,y)$ of generalized Lipschitz class by double Hausdorff matrix summability method

2020 ◽  
Vol 2020 (1) ◽  
Author(s):  
Abhishek Mishra ◽  
Vishnu Narayan Mishra ◽  
M. Mursaleen
Keyword(s):  
Double Fourier Series ◽  
Degree Of Approximation ◽  
Trigonometric Approximation ◽  
Lipschitz Class ◽  
Gamma Delta ◽  
Approximation Of Functions ◽  
Matrix Summability ◽  
Alpha Beta ◽  
Generalized Lipschitz Class ◽  
Hausdorff Matrix

AbstractIn this paper, we establish a new estimate for the degree of approximation of functions $f(x,y)$ f ( x , y ) belonging to the generalized Lipschitz class $Lip ((\xi _{1}, \xi _{2} );r )$ L i p ( ( ξ 1 , ξ 2 ) ; r ) , $r \geq 1$ r ≥ 1 , by double Hausdorff matrix summability means of double Fourier series. We also deduce the degree of approximation of functions from $Lip ((\alpha ,\beta );r )$ L i p ( ( α , β ) ; r ) and $Lip(\alpha ,\beta )$ L i p ( α , β ) in the form of corollary. We establish some auxiliary results on trigonometric approximation for almost Euler means and $(C, \gamma , \delta )$ ( C , γ , δ ) means.

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