Addition of nitrosonium ion to mercaptide-bridged binuclear iron(II) and cobalt(II) complexes

1974 ◽  
Vol 96 (20) ◽  
pp. 6519-6521 ◽  
Author(s):  
K. D. Karlin ◽  
D. L. Lewis ◽  
H. N. Rabinowitz ◽  
S. J. Lippard
Keyword(s):  
Binuclear Iron ◽  
Nitrosonium Ion

Oxidative addition of nitrosonium ion to sulfur-bridged binuclear iron(II) and cobalt(II) complexes

1977 ◽  
Vol 99 (5) ◽  
pp. 1420-1426 ◽  
Author(s):  
Harold N. Rabinowitz ◽  
Kenneth D. Karlin ◽  
Stephen J. Lippard
Keyword(s):  
Oxidative Addition ◽  
Binuclear Iron ◽  
Nitrosonium Ion

ChemInform Abstract: ADDITION OF NITROSONIUM ION TO MERCAPTIDE-BRIDGED BINUCLEAR IRON(II) AND COBALT(II) COMPLEXES

1974 ◽  
Vol 5 (50) ◽  
pp. no-no
Author(s):  
K. D. KARLIN ◽  
D. L. LEWIS ◽  
H. N. RABINOWITZ ◽  
S. J. LIPPARD
Keyword(s):  
Binuclear Iron ◽  
Nitrosonium Ion

scholarly journals Formation of Phenoxy Radical by Binuclear Iron(III) Complex and Hydrogen Peroxide System

1991 ◽  
Vol 20 (10) ◽  
pp. 1703-1706 ◽  
Author(s):  
Yuzo Nishida ◽  
Tetsuya Akamatsu ◽  
Miyuki Nasu
Keyword(s):  
Hydrogen Peroxide ◽  
Phenoxy Radical ◽  
Binuclear Iron

Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer: a highly efficient catalyst for biomimetic oxygenation reactions

2014 ◽  
Vol 55 (41) ◽  
pp. 5687-5690 ◽  
Author(s):  
Mekhman S. Yusubov ◽  
Cumali Celik ◽  
Margarita R. Geraskina ◽  
Akira Yoshimura ◽  
Viktor V. Zhdankin ◽  
...  
Keyword(s):  
Efficient Catalyst ◽  
Highly Efficient ◽  
Binuclear Iron

Binuclear Iron Carbonyls and Their Significance as Catalytic Intermediates1

1957 ◽  
Vol 79 (23) ◽  
pp. 6116-6121 ◽  
Author(s):  
Heinz W. Sternberg ◽  
Raymond Markby ◽  
Irving Wender
Keyword(s):  
Iron Carbonyls ◽  
Binuclear Iron

Synthesis, crystal structure, magnetic property, and nuclease activity of a binuclear iron(III) complex

2009 ◽  
Vol 62 (8) ◽  
pp. 1260-1270 ◽  
Author(s):  
Jing Qian ◽  
Jin-Lei Tian ◽  
Li Feng ◽  
Wen Gu ◽  
Xiao-Jun Zhao ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Magnetic Property ◽  
Nuclease Activity ◽  
Binuclear Iron

The Effects of Preparation Methods on Iron Structures of Iron-Supported HZSM-5 and their Catalytic Performance for Methanol Dehydration

2016 ◽  
Vol 723 ◽  
pp. 633-639
Author(s):  
Waenkaew Pantupho ◽  
Arthit Neramittagapong ◽  
Nuttawut Osakoo ◽  
Jatuporn Wittayakun ◽  
Sirinuch Loiha
Keyword(s):  
Flow Reactor ◽  
Fixed Bed ◽  
Catalytic Performance ◽  
Active Species ◽  
Iron Complex ◽  
Methanol Dehydration ◽  
Low Carbon ◽  
Zeolite Framework ◽  
Preparation Methods ◽  
Binuclear Iron

Iron-supported HZSM-5 catalysts were prepared by hydrothermal (Fe-HZSM-5_HYD) and impregnation methods (Fe/HZSM-5_IMP). The active species of binuclear-iron complex and iron-substituted zeolite framework, confirmed by EXAFS analysis, were observed on Fe/HZSM-5_IMP and Fe-HZSM-5_HYD, respectively. The catalysts were used for production of dimethyl ether (DME) by methanol dehydration at 200-350 °C using fixed bed flow reactor. Fe/HZSM-5_IMP showed higher catalytic conversion than Fe-HZSM-5_HYD. However, the Fe/HZSM-5_IMP catalyst was less selective to DME product and strongly deactivated for 24h. The deactivation might due to transformation of binuclear-iron to the a-iron site which was strong acidic strengh. The iron-substituted zeolite framework of Fe-HZSM-5_HYD showed high stability toward methanol dehydration. Moreover, the catalyst showed advantages of good selective to DME and low carbon deposition on surface. These results suggested that the iron-substituted zeolite framework structure could improve catalytic performance for mrthanol dehydration.

Sign in / Sign up

Export Citation Format

Share Document