Additions and Corrections - Stable Carbocations. CXXX. Carbon-13 Nuclear Magnetic Resonance Study of Halocarbenium Ions. Degree of Halogen "Back-Donation" and Relative Stability of Halocarbenium Ions.

1974 ◽  
Vol 96 (5) ◽  
pp. 1642-1642
Author(s):  
George Olah ◽  
Y. Mo ◽  
Y. Halpern
1987 ◽  
Vol 65 (10) ◽  
pp. 2434-2440 ◽  
Author(s):  
M. Madalena Caldeira ◽  
M. Luísa Ramos ◽  
Nuno C. Oliveira ◽  
Victor M. S. Gil

A proton, carbon-13, and vanadium-51 nuclear magnetic resonance study is reported on the number, stoichiometry, geometry, and relative stability of the complexes that form when vanadate(V) solutions are mixed with each one of the following organic α-hydroxyacids in the pH range ~2.5 – ~7: glycolic, lactic, chloro-3- and phenyl-3-lactic, mandelic, glyceric, and malic acids. The predominant complexes have 1:1 composition (almost certainly in a polymeric structure) in contrast with the 1:2 (metal:ligand) stoichiometry of the corresponding Mo(VI) and W(VI) complexes.


1999 ◽  
Vol 11 (3) ◽  
pp. 871-879 ◽  
Author(s):  
A Taye ◽  
G Klotzsche ◽  
D Michel ◽  
S Mulla-Osman ◽  
R Böttcher

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