Mass spectrometry in structural and stereochemical problems. CCXL. Effect of a 14.alpha.-angular methyl group upon the mass spectral fragmentation of 11- and 7-keto steroids

1973 ◽  
Vol 95 (26) ◽  
pp. 8726-8733 ◽  
Author(s):  
Richard R. Muccino ◽  
Carl. Djerassi
Keyword(s):  
Mass Spectrometry ◽  
Mass Spectral Fragmentation ◽  
Methyl Group ◽  
Mass Spectral

Massenspektrometrische Fragmentierung von Trimethylsilylderivaten (TMS) des Thyrotropin-„Releasing“-Hormons (TRH) und dessen Teilstrukturen / Mass Spectroscopy of Trimethylsilyl Derivatives of Thyrotropin-releasing Hormone and its Constituents

1973 ◽  
Vol 28 (11-12) ◽  
pp. 820-823 ◽  
Author(s):  
W. A. König ◽  
S. Fuchs ◽  
K. Zech ◽  
W. Voelter
Keyword(s):  
Mass Spectrometry ◽  
Mass Spectroscopy ◽  
Peptide Hormones ◽  
Thyrotropin Releasing Hormone ◽  
Mass Spectral Fragmentation ◽  
Releasing Hormone ◽  
Mass Spectral ◽  
Trimethylsilyl Derivatives ◽  
Fragmentation Patterns ◽  
Derivatives Of

The mass spectral fragmentation patterns of trimethylsilyl derivatives of TRH and its constituents are discussed. The utility of these derivatives for the control of the synthesis of peptide hormones by mass spectrometry is obvious.

Fragmentation pathways in the mass spectra of isomeric phenylazoxypyridine-N-oxides

1992 ◽  
Vol 70 (4) ◽  
pp. 1028-1032 ◽  
Author(s):  
Nigel J. Bunce ◽  
H. Stewart McKinnon ◽  
Randy J. Schnurr ◽  
Sam R. Keum ◽  
Erwin Buncel
Keyword(s):  
Mass Spectrometry ◽  
Tandem Mass Spectrometry ◽  
Electron Impact ◽  
Mass Spectra ◽  
Chemical Reduction ◽  
Ion Source ◽  
Tandem Mass ◽  
Mass Spectral Fragmentation ◽  
Fragmentation Pathways ◽  
Mass Spectral

The mass spectral fragmentation pathways of a series of phenylazoxypyridine-N-oxides have been studied under electron impact conditions using tandem mass spectrometry. Besides simple C—N cleavages, the azoxypyridine-N-oxides undergo deep-seated rearrangements directly from the molecular ion. In addition, the spectra are complicated by a purely chemical reduction of the N—O functionalities that occurs in the ion source prior to ionization.

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