Hydroxy ketone rearrangements. II. Kinetics and mechanism of the thermal rearrangements of optically active .alpha.-hydroxy ketones. Example of a cyclic three-component equilibrium

Calvin L. Stevens; Furman E. Glenn; P. Madhavan. Pillai

doi:10.1021/ja00800a024

Hydroxy ketone rearrangements. II. Kinetics and mechanism of the thermal rearrangements of optically active .alpha.-hydroxy ketones. Example of a cyclic three-component equilibrium

Journal of the American Chemical Society ◽

10.1021/ja00800a024 ◽

1973 ◽

Vol 95 (19) ◽

pp. 6301-6308 ◽

Cited By ~ 6

Author(s):

Calvin L. Stevens ◽

Furman E. Glenn ◽

P. Madhavan. Pillai

Keyword(s):

Optically Active ◽

Kinetics And Mechanism ◽

Hydroxy Ketone ◽

Thermal Rearrangements ◽

Hydroxy Ketones

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ChemInform Abstract: HYDROXY KETONE REARRANGEMENTS PART 2, KINETICS AND MECHANISM OF THE THERMAL REARRANGEMENTS OF OPTICALLY ACTIVE ALPHA-HYDROXY KETONES, EXAMPLE OF A CYCLIC THREE-COMPONENT EQUILIBRIUM

Chemischer Informationsdienst ◽

10.1002/chin.197347172 ◽

1973 ◽

Vol 4 (47) ◽

pp. no-no

Author(s):

CALVIN L. STEVENS ◽

FURNAN E. GLENN ◽

P. MADHAVAN PILLAI

Keyword(s):

Optically Active ◽

Kinetics And Mechanism ◽

Hydroxy Ketone ◽

Thermal Rearrangements ◽

Hydroxy Ketones

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Thermal rearrangements of methylenecyclobutanes. Degenerate rearrangement of optically active 1-(Z)-(1-deuterioethylidene)-2-methyl-trans-3,4,4-trideuteriocyclobutane

Journal of the American Chemical Society ◽

10.1021/ja00797a028 ◽

1973 ◽

Vol 95 (16) ◽

pp. 5261-5266 ◽

Cited By ~ 9

Author(s):

John E. Baldwin ◽

Ronald H. Fleming

Keyword(s):

Optically Active ◽

Thermal Rearrangements ◽

Degenerate Rearrangement

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ChemInform Abstract: Selective Oxidation of Optically Active sec,sec-1,2-Diols by Dioxiranes. A Practical Method for the Synthesis of Homochiral α- Hydroxy Ketones in High Optical Purity.

ChemInform ◽

10.1002/chin.199342086 ◽

2010 ◽

Vol 24 (42) ◽

pp. no-no

Author(s):

L. D'ACCOLTI ◽

A. DETOMASO ◽

C. FUSCO ◽

A. ROSA ◽

R. CURCI

Keyword(s):

Selective Oxidation ◽

Optical Purity ◽

Practical Method ◽

Optically Active ◽

High Optical Purity ◽

Hydroxy Ketones

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Stereoselectivity in reactions of metal complexes part XXI. Kinetics and mechanism of electron transfer between rac-[Co(L)H2O]+ (L = N,N′-[(pyridine-2,6-diyl)-bis(methylene)]bis[amino acid]) and optically active iron (II) complexes

Inorganica Chimica Acta ◽

10.1016/s0020-1693(98)00082-6 ◽

1998 ◽

Vol 275-276 ◽

pp. 1-8 ◽

Cited By ~ 2

Author(s):

Klaus Bernauer ◽

Deirdre Hugi-Cleary ◽

Hermann Josef Hilgers ◽

Habib Abd-el-Khalek ◽

Nadia Brügger ◽

...

Keyword(s):

Electron Transfer ◽

Amino Acid ◽

Metal Complexes ◽

Optically Active ◽

Kinetics And Mechanism ◽

Active Iron

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Stable carbonium ions. CIX. Protonation of hydroxy ketones in fluorosulfuric acid-antimony pentafluoride-sulfur dioxide solution and the study of hydroxy ketone-antimony pentafluoride complexes

The Journal of Organic Chemistry ◽

10.1021/jo00836a074 ◽

1970 ◽

Vol 35 (11) ◽

pp. 3922-3924 ◽

Cited By ~ 2

Author(s):

George A. Olah ◽

Alice T. Ku

Keyword(s):

Sulfur Dioxide ◽

Hydroxy Ketone ◽

Antimony Pentafluoride ◽

Carbonium Ions ◽

Hydroxy Ketones

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ChemInform Abstract: Synthesis of Optically Active α-Hydroxy Ketones by Enantioselective Oxidation of Silyl Enol Ethers with a Fructose-Derived Dioxirane.

ChemInform ◽

10.1002/chin.199828106 ◽

2010 ◽

Vol 29 (28) ◽

pp. no-no

Author(s):

W. ADAM ◽

R. T. FELL ◽

C. R. SAHA-MOELLER ◽

C.-G. ZHAO

Keyword(s):

Optically Active ◽

Enol Ethers ◽

Enantioselective Oxidation ◽

Silyl Enol Ethers ◽

Hydroxy Ketones

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Catalytic enantioselective Amadori–Heyns rearrangement of racemic α-hydroxy ketones with arylamines: synthesis of optically active α-arylamino ketones

Chemical Communications ◽

10.1039/c3cc45278f ◽

2013 ◽

Vol 49 (78) ◽

pp. 8812 ◽

Cited By ~ 20

Author(s):

Angelo Frongia ◽

Francesco Secci ◽

Francesca Capitta ◽

Pier Paolo Piras ◽

Maria Luisa Sanna

Keyword(s):

Optically Active ◽

Hydroxy Ketones

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Preparation of optically active α-hydroxy ketone derivatives by Enzyme-Mediated Hydrolysis of Enol Esters

Tetrahedron Letters ◽

10.1016/s0040-4039(00)97267-8 ◽

1990 ◽

Vol 31 (49) ◽

pp. 7159-7162 ◽

Cited By ~ 7

Author(s):

Kazutsugu Matsumoto ◽

Natsuko Suzuki ◽

Hiromichi Ohta

Keyword(s):

Optically Active ◽

Hydroxy Ketone ◽

Enol Esters ◽

Hydrolysis Of

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Stereoselective Synthesis of Optically Active α-Hydroxy Ketones andanti-1,2-Diols via Asymmetric Transfer Hydrogenation of Unsymmetrically Substituted 1,2-Diketones

Organic Letters ◽

10.1021/ol0002572 ◽

2000 ◽

Vol 2 (24) ◽

pp. 3833-3836 ◽

Cited By ~ 110

Author(s):

Takashi Koike ◽

Kunihiko Murata ◽

Takao Ikariya

Keyword(s):

Stereoselective Synthesis ◽

Optically Active ◽

Transfer Hydrogenation ◽

Asymmetric Transfer Hydrogenation ◽

Hydroxy Ketones

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Preparation of optically active 1,2-diols and .alpha.-hydroxy ketones using glycerol dehydrogenase as catalyst. Limits to enzyme-catalyzed synthesis due to noncompetitive and mixed inhibition by product

The Journal of Organic Chemistry ◽

10.1021/jo00351a005 ◽

1986 ◽

Vol 51 (1) ◽

pp. 25-36 ◽

Cited By ~ 98

Author(s):

Linda G. Lee ◽

George M. Whitesides

Keyword(s):

Optically Active ◽

Glycerol Dehydrogenase ◽

Mixed Inhibition ◽

Hydroxy Ketones

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