Metal ion catalysis of oxygen transfer reactions. III. Transition metal chelates as catalysts in the oxidation of nitrosobenzene. Oxygen transfer from alkyl peroxy radicals

1973 ◽  
Vol 95 (16) ◽  
pp. 5198-5204 ◽  
Author(s):  
Nelson A. Johnson ◽  
Edwin S. Gould
Keyword(s):  
Transition Metal ◽  
Oxygen Transfer ◽  
Metal Ion ◽  
Metal Chelates ◽  
Transfer Reactions ◽  
Peroxy Radicals ◽  
Transition Metal Chelates ◽  
Alkyl Peroxy Radicals ◽  
Metal Ion Catalysis

scholarly journals Stability Studies of Transition Metal Chelates of 5-Bromosalicylidene-4-methoxyaniline andSalicylidene-2,3-dimethylaniline as Ligands

2011 ◽  
Vol 8 (4) ◽  
pp. 1911-1915
Author(s):  
N. G. Nadkarni ◽  
K. V. Mangaonkar
Keyword(s):  
Ionic Strength ◽  
Transition Metal ◽  
Stability Constants ◽  
Metal Chelates ◽  
Ternary Complexes ◽  
Water Medium ◽  
Stability Studies ◽  
Binary And Ternary Complexes ◽  
Transition Metal Chelates ◽  
The Stability

Binary and ternary complexes of the type M-Y and M-X-Y [M = Mn(II), Ni(II), Cu(II) and Zn(II); X = 5-bromosalicylidene-4-methoxyaniline and Y = salicylidene-2,3-dimethylaniline] have been examined pH-metrically at 27±0.5°C and at constant ionic strength, μ = 0.1 M (KCl) in 75 : 25(v/v) 1,4-dioxne-water medium. The stability constants for binary (M-Y) and ternary (M-X-Y) systems were calculated.

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