Relaxation of excited state carbene to ground state. Internal heavy atom effect

1973 ◽  
Vol 95 (15) ◽  
pp. 5041-5042 ◽  
Author(s):  
P. S. Skell ◽  
S. J. Valenty ◽  
P. W. Humer
Keyword(s):  
Excited State ◽  
Ground State ◽  
Heavy Atom ◽  
Heavy Atom Effect ◽  
Atom Effect

Photochemical heavy-atom effect. 9. Spin-orbital effects on the excited-state cycloaddition of 5-acetoacenaphthylene to cyclopentadiene

1979 ◽  
Vol 44 (4) ◽  
pp. 514-519 ◽  
Author(s):  
Timothy E. O'Boyle ◽  
Lou J. Scott ◽  
Benjamin F. Plummer ◽  
P. S. Song
Keyword(s):  
Excited State ◽  
Heavy Atom ◽  
Spin Orbital ◽  
Heavy Atom Effect ◽  
Atom Effect

Competition between the heavy atom effect and vibronic coupling in donor–bridge–acceptor organometallics

2020 ◽  
Vol 22 (8) ◽  
pp. 4659-4667 ◽  
Author(s):  
Julien Eng ◽  
Stuart Thompson ◽  
Heather Goodwin ◽  
Dan Credgington ◽  
Thomas James Penfold
Keyword(s):  
Excited State ◽  
Quantum Dynamics ◽  
Heavy Atom ◽  
Vibronic Coupling ◽  
Intersystem Crossing ◽  
Heavy Atom Effect ◽  
Metal Amides ◽  
Coinage Metals ◽  
Dynamics Simulations ◽  
Atom Effect

The excited state properties and intersystem crossing dynamics of a series of donor–bridge–acceptor carbene metal-amides based upon the coinage metals Cu, Ag, Au, are investigated using quantum dynamics simulations and supported by photophysical characterisation.

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