Kinetics and mechanism of oxidative addition of iodine to platinum acetylacetonate in nonpolar solvents. Photochemically initiated free-radical chain pathway

1973 ◽  
Vol 95 (13) ◽  
pp. 4461-4463 ◽  
Author(s):  
D. Hopgood ◽  
R. A. Jenkins
Keyword(s):  
Free Radical ◽  
Oxidative Addition ◽  
Kinetics And Mechanism ◽  
Radical Chain ◽  
Nonpolar Solvents

Kinetics and mechanism of laser-driven powder synthesis from organosilane precursors

1989 ◽  
Vol 4 (6) ◽  
pp. 1538-1548 ◽  
Author(s):  
G. W. Rice ◽  
R. L. Woodin
Keyword(s):  
Free Radical ◽  
Bond Cleavage ◽  
Kinetics And Mechanism ◽  
Organosilicon Compounds ◽  
Qualitative Model ◽  
Powder Synthesis ◽  
Radical Chain ◽  
Chain Reactions ◽  
Large Molecules ◽  
Organosilicon Polymers

Laser-driven synthesis of refractory powders from the organosilicon compounds ((CH3)3Si)2NH and ((CH3)3Si)2O has been studied as prototypical of powder syntheses from large molecules. A cw CO2 laser is used for powder syntheses and pulsed TEA CO2 laser-driven homogeneous pyrolysis is used to study the initiation chemistry. Initial decomposition of the organosilanes by Si–C bond cleavage initiates free radical chain reactions which produce organosilicon polymers and subsequent refractory phases. A qualitative model is proposed which provides a framework for understanding the parameters influencing powder synthesis from large molecules.

ChemInform Abstract: New Free-Radical Chain Processes Involving Substitution of Vinyl and Aryl Chlorides by Alkanes, Alkenes, Esters, and Ethers.

ChemInform ◽  
2010 ◽  
Vol 28 (4) ◽  
pp. no-no
Author(s):  
S. ARANEO ◽  
R. ARRIGONI ◽  
H.-R. BJOERSVIK ◽  
F. FONTANA ◽  
L. LIGUORI ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Chain ◽  
Aryl Chlorides ◽  
Chain Processes

scholarly journals The detection and inhibition of free radical chain reactions

1942 ◽  
Vol 180 (982) ◽  
pp. 237-256 ◽  
Keyword(s):  
Nitric Oxide ◽  
Free Radical ◽  
Chemical Analysis ◽  
Diethyl Ether ◽  
Pressure Increase ◽  
Stationary States ◽  
Decomposition Rates ◽  
Radical Chain ◽  
Chain Reactions ◽  
Limiting Values

Part I. Comparison of nitric oxide and propylene as inhibitors The reduction by propylene of the rate of pressure increase in the decomposition of propaldehyde at 550° has been shown by chemical analysis to represent a true inhibition of the reaction, and not to be due n an important degree to an induced polymerization of the propylene. With propaldehyde and with diethyl ether the limiting values to which the decomposition rates are reduced by nitric oxide and by propylene respectively are the same, although much more propylene is required to produce a given degree of inhibition. From this it is concluded that the limiting rates are more probably those of independent non-chain processes, than those characteristic of stationary states where the inhibitor starts and stops chains with equal efficiency.

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