Mechanistic and kinetic studies at 10-11-10-5 sec of the unimolecular gas-phase reactions induced by field ionization of cyclohexene and cyclohexene-3,3,6,6-d4

1972 ◽  
Vol 94 (19) ◽  
pp. 6794-6802 ◽  
Author(s):  
P. J. Derrick ◽  
A. M. Falick ◽  
A. L. Burlingame
Keyword(s):  
Gas Phase ◽  
Kinetic Studies ◽  
Field Ionization ◽  
Gas Phase Reactions

A PANORAMIC MASS SPECTROSCOPE FOR KINETIC STUDIES

1955 ◽  
Vol 33 (2) ◽  
pp. 74-95 ◽  
Author(s):  
Edouard G. Leger
Keyword(s):  
Gas Phase ◽  
Diethyl Ether ◽  
Motion Picture ◽  
Chemical Species ◽  
Kinetic Studies ◽  
Mass Spectrometric ◽  
Gas Phase Reactions ◽  
Electron Multiplier ◽  
Cool Flames ◽  
Cathode Ray Tube

A mass spectroscope capable of recording the trend of many chemical species in rapid gas-phase reactions is described. The instrument represents a departure from analytical mass spectrometric practice by using a molecular streaming source, rapid electric scanning, an electron multiplier ion detector amplifier, and a cathode ray tube display. A 40 peak spectrum can be scanned in five milliseconds and recorded by a motion picture camera. A few results obtained with this instrument in the study of diethyl ether cool flames are given.

A jet-stirred reactor for kinetic studies of homogeneous gas-phase reactions at pressures up to ten atmospheres (≈1 MPa)

1986 ◽  
Vol 19 (3) ◽  
pp. 207-209 ◽  
Author(s):  
P Dagaut ◽  
M Cathonnet ◽  
J P Rouan ◽  
R Foulatier ◽  
A Quilgars ◽  
...  
Keyword(s):  
Gas Phase ◽  
Kinetic Studies ◽  
Gas Phase Reactions ◽  
Stirred Reactor

High‐temperature photochemistry reactor for kinetic studies of isolated elementary gas‐phase reactions

1980 ◽  
Vol 51 (2) ◽  
pp. 195-200 ◽  
Author(s):  
William Felder ◽  
Arthur Fontijn ◽  
Hermannn N. Volltrauer ◽  
David R. Voorhees
Keyword(s):  
High Temperature ◽  
Gas Phase ◽  
Kinetic Studies ◽  
Gas Phase Reactions

The kinetics of gas phase reactions studied in a "homogeneous reactor"

1988 ◽  
Vol 66 (9) ◽  
pp. 2325-2334 ◽  
Author(s):  
John M. Roscoe
Keyword(s):  
Gas Phase ◽  
Kinetic Studies ◽  
Gas Phase Reactions ◽  
Reaction Volume ◽  
First Order ◽  
Homogeneity Assumption ◽  
Good Spatial Resolution ◽  
Secondary Reactions ◽  
Homogeneous Reactor ◽  
Kinetics Of

The use of a "well-stirred" or "homogeneous" reactor in kinetic studies of gas phase reactions has been examined to assess the sensitivity of the method to the criteria upon which its use is based. The effects of heterogeneous and homogeneous secondary reactions are considered and the validity of the assumption of homogeneity has been examined experimentally for conditions similar to those which have been used elsewhere. The atom sink presented by the excess reagent under pseudo first order conditions results in failure of the homogeneity assumption. However, it is found that homogeneity is not required for successful use of the method provided the analytical measurements have good spatial resolution and the reaction volume is well-defined. The method is illustrated by using it to study some reactions of O(3P).

Kinetic studies of the gas-phase reactions of CN with O2 and H2 from 294 to 1000 K

1989 ◽  
Vol 154 (5) ◽  
pp. 449-453 ◽  
Author(s):  
B. Atakan ◽  
A. Jacobs ◽  
M. Wahl ◽  
R. Weller ◽  
J. Wolfrum
Keyword(s):  
Gas Phase ◽  
Kinetic Studies ◽  
Gas Phase Reactions
Sign in / Sign up

Export Citation Format

Share Document