Silyl radicals. IX. Cleavage of silicon-silicon and germanium-germanium bonds with 1,2-dibromoethane by a free-radical mechanism. Evidence for bimolecular homolytic substitution at silicon and germanium

1972 ◽  
Vol 94 (4) ◽  
pp. 1384-1385 ◽  
Author(s):  
Akira Hosomi ◽  
Hideki Sakurai
Keyword(s):  
Free Radical ◽  
Radical Mechanism ◽  
Free Radical Mechanism ◽  
Silyl Radicals ◽  
Silicon And Germanium ◽  
Silicon Silicon ◽  
Homolytic Substitution

Comparative QSAR evidence for a free-radical mechanism of phenol-induced toxicity

2000 ◽  
Vol 127 (1) ◽  
pp. 61-72 ◽  
Author(s):  
Corwin Hansch ◽  
Susan C. McKarns ◽  
Carr J. Smith ◽  
David J. Doolittle
Keyword(s):  
Free Radical ◽  
Radical Mechanism ◽  
Free Radical Mechanism

Dirhodium(II)-Catalyzed Diamination Reaction via a Free Radical Pathway

2021 ◽  
Author(s):  
Zhiying Fan ◽  
Zhifan Wang ◽  
Ruoyi Shi ◽  
Yuanhua Wang
Keyword(s):  
Free Radical ◽  
Bond Formation ◽  
Mechanistic Study ◽  
Radical Mechanism ◽  
Free Radical Mechanism

Unlike C-N bond formation with classical dirhodium(II)-nitrenoids as the key intermediate, dirhodium(II)-catalyzed 1,2-and 1,3-diamination reactions are realized by a free radical mechanism. A mechanistic study revealed that the reactions undergo...

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