Nucleophilic and metal ion acceleration of ester hydrolysis in a hydrophobic complex. Reactive enzyme model system

1972 ◽  
Vol 94 (4) ◽  
pp. 1376-1377 ◽  
Author(s):  
Robert Hershfield ◽  
Myron L. Bender
Keyword(s):  
Metal Ion ◽  
Model System ◽  
Ester Hydrolysis ◽  
Ion Acceleration ◽  
Enzyme Model

scholarly journals Transmembrane signal transduction by cofactor transport

2021 ◽  
Author(s):  
Istvan Kocsis ◽  
Yudi Ding ◽  
Nicholas H. Williams ◽  
Christopher A. Hunter
Keyword(s):  
Signal Transduction ◽  
Lipid Bilayer ◽  
Metal Ion ◽  
Bilayer Membrane ◽  
Ester Hydrolysis ◽  
Lipid Bilayer Membrane ◽  
Metal Ion Cofactors

Synthetic transducers transport externally added metal ion cofactors across the lipid bilayer membrane of vesicles to trigger catalysis of ester hydrolysis in the inner compartment. Signal transduction activity is modulated by hydrazone formation.

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