Conformation of cyclononane. Evidence from 251-MHz proton nuclear magnetic resonance and 63-MHz carbon-13 Fourier transform nuclear magnetic resonance

1971 ◽  
Vol 93 (20) ◽  
pp. 5266-5268 ◽  
Author(s):  
F. A. L. Anet ◽  
J. J. Wagner
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Fourier Transform ◽  
Magnetic Resonance ◽  
Proton Nuclear Magnetic Resonance ◽  
Nuclear Magnetic

Study of Configurational Sequence Structures of Poly(Butadiene)s by Carbon-13 Proton Decoupled Fourier Transform Nuclear Magnetic Resonance Spectroscopy

1973 ◽  
Vol 46 (2) ◽  
pp. 350-358 ◽  
Author(s):  
Yasuhide Alaki ◽  
Toshio Yoshimoto ◽  
Mamoru Imanari ◽  
Makoto Takeuchi
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Fourier Transform ◽  
Magnetic Resonance ◽  
Magnetic Resonance Spectroscopy ◽  
Polymer Chains ◽  
Proton Nuclear Magnetic Resonance ◽  
Resonance Spectroscopy ◽  
Sequence Structure ◽  
Nmr Method ◽  
Nuclear Magnetic

Abstract Carbon-13 proton nuclear magnetic resonance (NMR) of poly(butadiene) s consisting of various ratios of cis-1,4-, trans-1,4- and 1,2-structures were measured by the pulsed Fourier transform NMR method. The spectra of poly(butadiene)s with two or three kinds of butadiene configurations show several new signals which were not observed for homopolymers comprising merely one kind of butadiene configuration. All of these peaks are ascribed to the carbons linked by different kinds of configurations. From these results, the configurational sequence structure of butadiene units in polymer chains has been revealed.

Residual Hydrogen Determination in Perfluoropolyalkylethers Using Fourier Transform Infrared and Proton Nuclear Magnetic Resonance Spectroscopies

1995 ◽  
Vol 49 (10) ◽  
pp. 1474-1477 ◽  
Author(s):  
Jim Liang ◽  
Mark Roselius ◽  
David W. Johnson
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Fourier Transform ◽  
Magnetic Resonance ◽  
Fourier Transform Infrared ◽  
Proton Nuclear Magnetic Resonance ◽  
Linear Calibration ◽  
Standard Samples ◽  
Residual Hydrogen ◽  
Ft Ir ◽  
Nuclear Magnetic

The residual hydrogen content of several perfluoropolyalkylether base fluids has been determined with the use of proton nuclear magnetic resonance (NMR) and Fourier transform infrared (FT-IR) spectroscopies. The analysis of standard samples gives a linear calibration curve for hydrogen concentrations between 0.5 and 500 ppm for both FT-IR and NMR. The two methods have similar detection limits of about 1 ppm. Analysis of identical samples of Krytox 143 AC and Krytox 143 AZ by both methods gives results which are in excellent agreement. The two methods also provide information about the chemical environment in which the hydrogen is located. In both of the Krytox samples, the hydrogen is located in CFH groups within the polymer chain.

The electropolymerization of N,N′-(propane-1,3-diyl)bis(2-aminobenzamide), characterization, and capacitor study

2018 ◽  
Vol 30 (1) ◽  
pp. 82-93 ◽  
Author(s):  
Murat Ates ◽  
Hakan Kolancilar ◽  
Sinan Caliskan ◽  
Damla Cinar
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Fourier Transform ◽  
Magnetic Resonance ◽  
Electrochemical Impedance ◽  
Fourier Transform Infrared ◽  
Attenuated Total Reflection ◽  
Proton Nuclear Magnetic Resonance ◽  
Capacitive Properties ◽  
Scan Rate ◽  
Nuclear Magnetic

In this study, aniline-based monomer, N, N′-(propane-1,3-diyl)bis(2-aminobenzamide), (PAB), was synthesized and characterized by proton nuclear magnetic resonance (1H-NMR), carbon-13 nuclear magnetic resonance (13C-NMR), and Fourier transform infrared spectroscopy. The electropolymerization of the monomer was performed on glassy carbon electrode by cyclic voltammetry (CV). The effects of solvent, dopant, scan number, and scan rate on the electropolymerization and properties of the poly(PAB) films were investigated. The modified electrode was also characterized by Fourier transform infrared-attenuated total reflection spectroscopy and scanning electron microscopy–energy-dispersive X-ray analysis. The capacitive properties of the poly(PAB) films were firstly tested by electrochemical impedance spectroscopy. The highest specific capacitances ( Csp) of poly(PAB) films were obtained as Csp = 6.22 mF cm−2 in 0.1 M lithium perchlorate/acetonitrile (ACN) for [PAB]0 = 20 mmol dm−3 and Csp = 16.9 mF cm−2 in 1 mol dm−3 sulfuric acid for [PAB]0 = 5 mmol dm−3 at the scan rate of 5 mV s−1 from CV measurements. This study is novel because it was the first study on capacitance performances of poly(PAB) films in the literature.

scholarly journals N-[7-Chloro-4-[4-(phenoxymethyl)-1H-1,2,3-triazol-1-yl] quinoline]-acetamide

Molbank ◽  
10.3390/m1213 ◽  
2021 ◽  
Vol 2021 (2) ◽  
pp. M1213
Author(s):  
Paolo Coghi ◽  
Jerome P. L. Ng ◽  
Ali Adnan Nasim ◽  
Vincent Kam Wai Wong
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Magnetic Resonance ◽  
Quantum Coherence ◽  
Biologically Active ◽  
Proton Nuclear Magnetic Resonance ◽  
Dipolar Cycloaddition ◽  
Heteronuclear Single Quantum Coherence ◽  
Pharmacokinetic Properties ◽  
Nuclear Magnetic

The 1,2,3-triazole is a well-known biologically active pharmacophore constructed by the copper-catalyzed azide–alkyne cycloaddition. We herein reported the synthesis of 4-amino-7-chloro-based [1,2,3]-triazole hybrids via Cu(I)-catalyzed Huisgen 1,3-dipolar cycloaddition of 4-azido-7-chloroquinoline with an alkyne derivative of acetaminophen. The compound was fully characterized by Fourier-transform infrared (FTIR), proton nuclear magnetic resonance (1H-NMR), carbon-13 nuclear magnetic resonance (13C-NMR), heteronuclear single quantum coherence (HSQC), ultraviolet (UV) and high-resolution mass spectroscopies (HRMS). This compound was screened in vitro with different normal and cancer cell lines. The drug likeness of the compound was also investigated by predicting its pharmacokinetic properties.

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