Application of electron spin resonance spectroscopy to problems of structure and conformation. XXIII. Ion pairing in alkali metal salts of biacetyl and perfluorobiacetyl. Mechanism of the homogeneous reduction of an .alpha.-diketone by lithium metal and an example of a remarkably slow equilibration

1971 ◽  
Vol 93 (16) ◽  
pp. 4088-4089 ◽  
Author(s):  
Glen A. Russell ◽  
John L. Gerlock ◽  
David F. Lawson
1971 ◽  
Vol 49 (12) ◽  
pp. 2059-2063 ◽  
Author(s):  
S. A. Al-Baldawi ◽  
T. E. Gough

Electron spin resonance spectroscopy has been used to study triple ions formed between pyrazine and tetramethylpyrazine and the cations Li+, Na+, K+ in dimethoxyethane, tetrahydrofuran, and 2-methyl-tetrahydrofuran. Differential line-broadening effects are reported within the hyperfine splitting patterns of the alkali metals incorporated into the triple ions, and a possible application of such effects to the study of ionic association is described.


2012 ◽  
Vol 47 (8) ◽  
pp. 640-643 ◽  
Author(s):  
Wanwisa Sudprasert ◽  
Sahakan Monthonwattana ◽  
Arag Vitittheeranon

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