Electron transfer through organic structural units. X. Catalysis, by pyridine derivatives of outer-sphere reductions of cobalt(III). Evidence for an unusually reactive outer-sphere reducing agent

1971 ◽  
Vol 93 (16) ◽  
pp. 4045-4047 ◽  
Author(s):  
Edwin S. Gould ◽  
John R. Barber
Keyword(s):  
Electron Transfer ◽  
Outer Sphere ◽  
Reducing Agent ◽  
Pyridine Derivatives ◽  
Structural Units ◽  
Derivatives Of

Electron transfer. 24. Catalysis of outer-sphere reactions by noncoordinated pyridine derivatives

1977 ◽  
Vol 99 (4) ◽  
pp. 1073-1077 ◽  
Author(s):  
Y. T. Fanchiang ◽  
R. R. Carlson ◽  
P. K. Thamburaj ◽  
Edwin S. Gould
Keyword(s):  
Electron Transfer ◽  
Outer Sphere ◽  
Pyridine Derivatives

ChemInform Abstract: ELECTRON TRANSFER. 24. CATALYSIS OF OUTER-SPHERE REACTIONS BY NONCOORDINATED PYRIDINE DERIVATIVES

1977 ◽  
Vol 8 (18) ◽  
pp. no-no
Author(s):  
Y.-T. FANCHIANG ◽  
R. R. CARLSON ◽  
P. K. THAMBURAJ ◽  
E. S. GOULD
Keyword(s):  
Electron Transfer ◽  
Outer Sphere ◽  
Pyridine Derivatives

scholarly journals RuIII(edta) complexes as molecular redox catalysts in chemical and electrochemical reduction of dioxygen and hydrogen peroxide: inner-sphere versus outer-sphere mechanism

RSC Advances ◽  
2021 ◽  
Vol 11 (35) ◽  
pp. 21359-21366
Author(s):  
Debabrata Chatterjee ◽  
Marta Chrzanowska ◽  
Anna Katafias ◽  
Maria Oszajca ◽  
Rudi van Eldik
Keyword(s):  
Hydrogen Peroxide ◽  
Electron Transfer ◽  
Electrochemical Reduction ◽  
Molecular Oxygen ◽  
Outer Sphere ◽  
Transfer Processes ◽  
Edta Complexes ◽  
Inner Sphere ◽  
Electron Transfer Processes ◽  
Sphere Mechanism

[RuII(edta)(L)]2–, where edta4– =ethylenediaminetetraacetate; L = pyrazine (pz) and H2O, can reduce molecular oxygen sequentially to hydrogen peroxide and further to water by involving both outer-sphere and inner-sphere electron transfer processes.

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