Solvent effects on strong charge-transfer complexes. IV. Trimethylamine and sulfur dioxide in the vapor phase

1971 ◽  
Vol 93 (1) ◽  
pp. 20-23 ◽  
Author(s):  
Just Grundnes ◽  
Sherril D. Christian ◽  
Venghuot Cheam ◽  
Sutton B. Farnham
Keyword(s):  
Charge Transfer ◽  
Sulfur Dioxide ◽  
Vapor Phase ◽  
Solvent Effects ◽  
Charge Transfer Complexes

Vapor-phase charge-transfer complexes. 12. Dimethyl ether – iodine

1984 ◽  
Vol 62 (4) ◽  
pp. 814-821
Author(s):  
S. J. Lo ◽  
M. Tamres
Keyword(s):  
Charge Transfer ◽  
Thermodynamic Properties ◽  
Dimethyl Ether ◽  
Diethyl Ether ◽  
Vapor Phase ◽  
Solvent Effects ◽  
Charge Transfer Complexes ◽  
Iodine Complex ◽  
Activity Method

Both a modified Benesi–Hildebrand method and the constant activity method were used to study the spectral and thermodynamic properties of the dimethyl ether – iodine complex in the vapor phase and in n-heptane solution. Comparison is made of these results with those for the diethyl ether – iodine complex. The solvent effects on ether – iodine, a relatively weak complex, are compared with those on stronger complexes.

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