.sigma.-.pi. Conjugation of carbon-metal bonds. Stereoelectronic and inductive effects

1970 ◽  
Vol 92 (25) ◽  
pp. 7476-7477 ◽  
Author(s):  
Teddy G. Traylor ◽  
Walter G. Hanstein ◽  
H. J. Berwin
Keyword(s):  
Inductive Effects ◽  
Pi Conjugation ◽  
Metal Bonds

scholarly journals An ab initio investigation of alkali–metal non-covalent bonds B⋯LiR and B⋯NaR (R = F, H or CH3) formed with simple Lewis bases B: the relative inductive effects of F, H and CH3

2020 ◽  
Vol 22 (28) ◽  
pp. 16421-16430 ◽  
Author(s):  
Ibon Alkorta ◽  
J. Grant Hill ◽  
Anthony C. Legon
Keyword(s):  
Alkali Metal ◽  
Ab Initio ◽  
Covalent Bonds ◽  
Lewis Bases ◽  
Inductive Effects ◽  
Non Covalent Interactions ◽  
Metal Bonds ◽  
Covalent Interactions

Alkali–metal bonds formed by LiR and NaR (R = F, H, CH3) with each of the Lewis bases OC, HCN, H2O, H3N, H2S and H3P are investigated ab initio at the CCSD(T)/AVTZ and CCSD(T)/awCVTZ levels to characterise these non-covalent interactions.

Compounds with Unbridged Dative Metal−Metal Bonds of Formula (R3P)2(OC)3OsW(CO)5and Related Complexes

2000 ◽  
Vol 19 (24) ◽  
pp. 5049-5062 ◽  
Author(s):  
Faming Jiang ◽  
Hilary A. Jenkins ◽  
Kumar Biradha ◽  
Harry B. Davis ◽  
Roland K. Pomeroy ◽  
...  
Keyword(s):  
Metal Metal ◽  
Metal Metal Bonds ◽  
Metal Bonds

ChemInform Abstract: STRUCTURE OF FLUOROMETHYL RADICALS. CONJUGATIVE AND INDUCTIVE EFFECTS

1978 ◽  
Vol 9 (25) ◽  
Author(s):  
F. BERNARDI ◽  
W. CHERRY ◽  
S. SHAIK ◽  
N. D. EPIOTIS
Keyword(s):  
Inductive Effects ◽  
Abstract Structure
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