Additions and Corrections - N1'-Methylthiaminium Diiodide. Model Study on the Effect of Coenzyme Bound Positive Charge on Reaction Mechanism Requiring Thiamin Pyrophosphate

1980 ◽  
Vol 102 (25) ◽  
pp. 7618-7618 ◽  
Author(s):  
Frank Jordan ◽  
Yitbarek Mariam
Keyword(s):  
Reaction Mechanism ◽  
Positive Charge ◽  
Model Study ◽  
Thiamin Pyrophosphate

Structure dependence and reaction mechanism of CO oxidation: A model study on macroporous CeO2 and CeO2-ZrO2 catalysts

2016 ◽  
Vol 344 ◽  
pp. 365-377 ◽  
Author(s):  
Yane Zheng ◽  
Kongzhai Li ◽  
Hua Wang ◽  
Yuhao Wang ◽  
Dong Tian ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Co Oxidation ◽  
Structure Dependence ◽  
Model Study

A model study on the photochemical isomerization of cyclic silenes

2015 ◽  
Vol 17 (7) ◽  
pp. 5039-5042 ◽  
Author(s):  
Ming-Der Su
Keyword(s):  
Reaction Mechanism ◽  
Photochemical Reaction ◽  
Membered Ring ◽  
Conical Intersection ◽  
Step Process ◽  
Model Study ◽  
One Step ◽  
Photochemical Isomerization

The photomigration reaction mechanism for a five-membered-ring silene 1 was theoretically studied using the CAS/6-311G(d) and MP2-CAS/6-311++G(3df,3pd) methods. The model computations conclude that the conical intersection mechanism plays an important role in such a photochemical reaction. That is, the conical intersection mechanism is a one-step process that has no barrier.

Arylation of enelactams using TIPSOTf: reaction scope and mechanistic insight

2021 ◽  
Author(s):  
Tomasz J. Idzik ◽  
Zofia M. Myk ◽  
Łukasz Struk ◽  
Magdalena Perużyńska ◽  
Gabriela Maciejewska ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Multinuclear Nmr ◽  
Mechanistic Insight ◽  
Nmr Study ◽  
Wide Range

Triisopropylsilyltrifluoromethanesulfonate can be effectively used for the arylation of a wide range of enelactams. The multinuclear NMR study provided deep insights into the reaction mechanism.

Social Desirability in Personality Inventories

2014 ◽  
Vol 35 (3) ◽  
pp. 144-157 ◽  
Author(s):  
Martin Bäckström ◽  
Fredrik Björklund
Keyword(s):  
Social Desirability ◽  
Big Five ◽  
Work Performance ◽  
Factor Model ◽  
Five Factor Model ◽  
Peer Ratings ◽  
Personality Inventories ◽  
Model Study ◽  
The Difference ◽  
New Variables

The difference between evaluatively loaded and evaluatively neutralized five-factor inventory items was used to create new variables, one for each factor in the five-factor model. Study 1 showed that these variables can be represented in terms of a general evaluative factor which is related to social desirability measures and indicated that the factor may equally well be represented as separate from the Big Five as superordinate to them. Study 2 revealed an evaluative factor in self-ratings and peer ratings of the Big Five, but the evaluative factor in self-reports did not correlate with such a factor in ratings by peers. In Study 3 the evaluative factor contributed above the Big Five in predicting work performance, indicating a substance component. The results are discussed in relation to measurement issues and self-serving biases.

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