Tautomeric catecholate-semiquinone interconversion via metal-ligand electron transfer. Structural, spectral, and magnetic properties of (3,5-di-tert-butylcatecholato)(3,5-di-tert-butylsemiquinone)(bipyridyl)cobalt(III), a complex containing mixed-valence organic ligands

1980 ◽  
Vol 102 (15) ◽  
pp. 4951-4957 ◽  
Author(s):  
Robert M. Buchanan ◽  
Cortlandt G. Pierpont
Keyword(s):  
Electron Transfer ◽  
Magnetic Properties ◽  
Mixed Valence ◽  
Organic Ligands ◽  
Metal Ligand

Electron transfer in mixed-valence tetranuclear iron clusters. Orbital effects and magnetic properties

1993 ◽  
Vol 177 (1) ◽  
pp. 15-22 ◽  
Author(s):  
J.J. Borrás-Almenar ◽  
E. Coronado ◽  
R. Georges ◽  
C.J. Gomez-García
Keyword(s):  
Electron Transfer ◽  
Magnetic Properties ◽  
Mixed Valence ◽  
Iron Clusters

Electrons in Molecules

2018 ◽  
Author(s):  
Jean-Pierre Launay ◽  
Michel Verdaguer
Keyword(s):  
Electron Transfer ◽  
Magnetic Properties ◽  
Molecular Electronics ◽  
Single Molecule ◽  
Field Effect Transistors ◽  
Photophysical Properties ◽  
Mixed Valence ◽  
Molecular Machines ◽  
Hybrid Form ◽  
Band Theory

The book treats in a unified way electronic properties of molecules (magnetic, electrical, photophysical), culminating with the mastering of electrons, i.e. molecular electronics and spintronics and molecular machines. Chapter 1 recalls basic concepts. Chapter 2 describes the magnetic properties due to localized electrons. This includes phenomena such as spin cross-over, exchange interaction from dihydrogen to extended molecular magnetic systems, and magnetic anisotropy with single-molecule magnets. Chapter 3 is devoted to the electrical properties due to moving electrons. One considers first electron transfer in discrete molecular systems, in particular in mixed valence compounds. Then, extended molecular solids, in particular molecular conductors, are described by band theory. Special attention is paid to structural distortions (Peierls instability) and interelectronic repulsions in narrow-band systems. Chapter 4 treats photophysical properties, mainly electron transfer in the excited state and its applications to photodiodes, organic light emitting diodes, photovoltaic cells and water photolysis. Energy transfer is also treated. Photomagnetism (how a photonic excitation modifies magnetic properties) is introduced. Finally, Chapter 5 combines the previous knowledge for three advanced subjects: first molecular electronics in its hybrid form (molecules connected to electrodes acting as wires, diodes, memory elements, field-effect transistors) or in the quantum computation approach. Then, molecular spintronics, using, besides the charge, the spin of the electron. Finally the theme of molecular machines is presented, with the problem of the directionality control of their motion.

Role of the Electron Transfer and Magnetic Exchange Interactions in the Magnetic Properties of Mixed-Valence Polyoxovanadate Complexes

2008 ◽  
Vol 47 (13) ◽  
pp. 5889-5901 ◽  
Author(s):  
Carmen J. Calzado ◽  
Juan M. Clemente-Juan ◽  
Eugenio Coronado ◽  
Alejandro Gaita-Arino ◽  
Nicolas Suaud
Keyword(s):  
Electron Transfer ◽  
Magnetic Properties ◽  
Mixed Valence ◽  
Exchange Interactions ◽  
Magnetic Exchange

Electron transfer in tetranuclear mixed-valence iron clusters. Role of the topology on the magnetic properties

1992 ◽  
Vol 166 (1-2) ◽  
pp. 139-144 ◽  
Author(s):  
J.J. Borras-Almenar ◽  
E. Coronado ◽  
R. Georges ◽  
C.J. Gomez-Garcia
Keyword(s):  
Electron Transfer ◽  
Magnetic Properties ◽  
Mixed Valence ◽  
Iron Clusters

Intramolecular Electron Transfer Mediated by a Tetrathiafulvalene Bridge in a Purely Organic Mixed-Valence System

2003 ◽  
Vol 42 (24) ◽  
pp. 2765-2768 ◽  
Author(s):  
Nicolas Gautier ◽  
Frédéric Dumur ◽  
Vega Lloveras ◽  
José Vidal-Gancedo ◽  
Jaume Veciana ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Mixed Valence ◽  
Intramolecular Electron Transfer
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