Transient species in photochemistry of enones. The orthogonal triplet state revealed by laser photolysis

1980 ◽  
Vol 102 (11) ◽  
pp. 3816-3822 ◽  
Author(s):  
Roland Bonneau
1999 ◽  
Vol 42 (6) ◽  
pp. 561-566 ◽  
Author(s):  
Qinhua Song ◽  
Yeping Xu ◽  
Shuqin Yu ◽  
Congxiang Chen ◽  
Xingxiao Ma ◽  
...  

1987 ◽  
Vol 19 (8) ◽  
pp. 999-1001 ◽  
Author(s):  
Keiji Imagi ◽  
Noriaki Ikeda ◽  
Hiroshi Masuhara ◽  
Masahiko Nishigaki ◽  
Masataka Isogawa

1979 ◽  
Vol 70 (10) ◽  
pp. 4673-4680 ◽  
Author(s):  
Kenneth P. Gross ◽  
Dennis M. Guthals ◽  
Joseph W. Nibler

2004 ◽  
Vol 57 (1) ◽  
pp. 101 ◽  
Author(s):  
Kiah H. Ang ◽  
Matthew Cox ◽  
Warren D. Lawrance ◽  
Rolf Prager ◽  
Jason A. Smith ◽  
...  

The first step in the photochemical decarboxylation of isoxazolones is the formation of the triplet state of the isoxazolone. We present evidence for the first time from flash laser photolysis of the lifetime of such species, and examples of their capture by solvent and by intramolecular cycloaddition.


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