An unusually long cobalt-carbon bond. Molecular structure of trans-bis(dimethylglyoximato)(isopropyl)(pyridine)cobalt(III). Implications with regard to the conformational trigger mechanism of cobalt-carbon bond cleavage in coenzyme B12

Luigi G. Marzilli; Paul J. Toscano; Lucio Randaccio; Nevenka Bresciani-Pahor; Mario Calligaris

doi:10.1021/ja00516a049

An unusually long cobalt-carbon bond. Molecular structure of trans-bis(dimethylglyoximato)(isopropyl)(pyridine)cobalt(III). Implications with regard to the conformational trigger mechanism of cobalt-carbon bond cleavage in coenzyme B12

Journal of the American Chemical Society ◽

10.1021/ja00516a049 ◽

1979 ◽

Vol 101 (22) ◽

pp. 6754-6756 ◽

Cited By ~ 44

Author(s):

Luigi G. Marzilli ◽

Paul J. Toscano ◽

Lucio Randaccio ◽

Nevenka Bresciani-Pahor ◽

Mario Calligaris

Keyword(s):

Molecular Structure ◽

Bond Cleavage ◽

Coenzyme B12 ◽

Trigger Mechanism ◽

Carbon Bond

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ChemInform Abstract: AN UNUSUALLY LONG COBALT-CARBON BOND. MOLECULAR STRUCTURE OF TRANS-BIS(DIMETHYLGLYOXIMATO)(ISOPROPYL)(PYRIDINE)COBALT(III). IMPLICATIONS WITH REGARD TO THE CONFORMATIONAL TRIGGER MECHANISM OF COBALT-CARBON BOND CLEAVAGE IN COENZYME B1

Chemischer Informationsdienst ◽

10.1002/chin.198005082 ◽

1980 ◽

Vol 11 (5) ◽

Author(s):

L. G. MARZILLI ◽

P. J. TOSCANO ◽

L. RANDACCIO ◽

N. BRESCIANI-PAHOR ◽

M. CALLIGARIS

Keyword(s):

Molecular Structure ◽

Bond Cleavage ◽

Trigger Mechanism ◽

Carbon Bond

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Reactivity of cyclopalladated compounds. Part 12. Insertion of 3,3-dimethylcyclopropenes into the palladium-carbon bond of cyclopalladated dimethylbenzylamine, leading to carbon-carbon bond cleavage or cyclopropyl ring retention. X-ray crystal and molecular structure of [cyclic][Pd[C(CO2Me)CMe2CHC6H4CH2NMe2]pyCl]

Organometallics ◽

10.1021/om00138a041 ◽

1986 ◽

Vol 5 (7) ◽

pp. 1511-1513 ◽

Cited By ~ 12

Author(s):

Fida. Maassarani ◽

Michel. Pfeffer ◽

Guy. Le Borgne ◽

Daniel. Grandjean

Keyword(s):

Molecular Structure ◽

Crystal And Molecular Structure ◽

Bond Cleavage ◽

Carbon Bond ◽

X Ray ◽

Carbon Carbon Bond ◽

Cyclopalladated Compounds

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Crystal and molecular structure of carbonylchlorobis(trimethylphosphine)-(1,2,3-triphenylpropenylium-1,3-diyl)iridium(1+) tetrafluoroborate(1-)-dichloromethane, [Ir(C3(C6H5)3)Cl(CO)(P(CH3)3)2][BF4].CH2Cl2, an oxidative addition derivative formed by carbon-carbon bond cleavage

Inorganic Chemistry ◽

10.1021/ic50115a051 ◽

1972 ◽

Vol 11 (9) ◽

pp. 2237-2242 ◽

Cited By ~ 32

Author(s):

R. M. Tuggle ◽

D. L. Weaver

Keyword(s):

Molecular Structure ◽

Crystal And Molecular Structure ◽

Bond Cleavage ◽

Oxidative Addition ◽

Carbon Bond ◽

Carbon Carbon Bond

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A platinum-promoted ring-opening reaction of hexakistrifluoromethylbenzene involving carbon–carbon bond cleavage; crystal and molecular structure of bis(t-butyl isocyanide)platinacyclohepta-cis-2,cis-4,cis-6-triene

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39750000723 ◽

1975 ◽

pp. 723-724 ◽

Cited By ~ 22

Author(s):

Jane Browning ◽

Michael Green ◽

Antonio Laguna ◽

Lesley E. Smart ◽

John L. Spencer ◽

...

Keyword(s):

Molecular Structure ◽

Ring Opening ◽

Crystal And Molecular Structure ◽

Bond Cleavage ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Ring Opening Reaction

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ChemInform Abstract: A VERY LONG COBALT TO NITROGEN BOND IN A COENZYME B12 MODEL. RELEVANCE TO THE ROLE OF THE 5,6-DIMETHYLBENZIMIDAZOLE IN COBALT-CARBON BOND CLEAVAGE IN COENZYME B12

Chemischer Informationsdienst ◽

10.1002/chin.198401299 ◽

1984 ◽

Vol 15 (1) ◽

Author(s):

M. F. SUMMERS ◽

P. J. TOSCANO ◽

N. BRESCIANI-PAHOR ◽

G. NARDON ◽

L. RANDACCIO ◽

...

Keyword(s):

Bond Cleavage ◽

Coenzyme B12 ◽

Carbon Bond ◽

Nitrogen Bond

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Angular distortions at the carbon bound to cobalt in coenzyme B12 models. Implications with regard to cobalt-carbon bond cleavage in coenzyme B12 and other alkylcobalamins

Journal of the American Chemical Society ◽

10.1021/ja00411a014 ◽

1981 ◽

Vol 103 (21) ◽

pp. 6347-6351 ◽

Cited By ~ 31

Author(s):

Lucio Randaccio ◽

Nevenka Bresciani-Pahor ◽

Paul J. Toscano ◽

Luigi G. Marzilli

Keyword(s):

Bond Cleavage ◽

Coenzyme B12 ◽

Carbon Bond

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A very long cobalt to nitrogen bond in a coenzyme B12 model. Relevance to the role of the 5,6-dimethylbenzimidazole in cobalt-carbon bond cleavage in coenzyme B12

Journal of the American Chemical Society ◽

10.1021/ja00358a012 ◽

1983 ◽

Vol 105 (20) ◽

pp. 6259-6263 ◽

Cited By ~ 38

Author(s):

Michael F. Summers ◽

Paul J. Toscano ◽

Nevenka Bresciani-Pahor ◽

Giorgio Nardin ◽

Lucio Randaccio ◽

...

Keyword(s):

Bond Cleavage ◽

Coenzyme B12 ◽

Carbon Bond ◽

Nitrogen Bond

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Carbonhydrogen and phosphoruscarbon bond cleavage of bis(dimethylphosphino)methane in triruthenium clusters: the molecular structure of [Ru3(CO)9(μ-H)(μ3-η3-Me2PCHPMe2)]

Journal of Organometallic Chemistry ◽

10.1016/0022-328x(87)85137-9 ◽

1987 ◽

Vol 332 (1-2) ◽

pp. 201-211 ◽

Cited By ~ 11

Author(s):

Ljbica Manojlović-Muir ◽

Dee Ann Brandes ◽

Richard J. Puddephatt

Keyword(s):

Molecular Structure ◽

Bond Cleavage ◽

Carbon Bond

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Multiple carbon–carbon bond cleavage on a heptaosmium cluster: synthesis and molecular structure of [Os7(CO)15(µ3-CPh)4]

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39880000972 ◽

1988 ◽

pp. 972-973 ◽

Cited By ~ 7

Author(s):

Brian F. G. Johnson ◽

Jack Lewis ◽

Julie A. Lunniss ◽

Dario Braga ◽

Fabrizia Grepioni

Keyword(s):

Molecular Structure ◽

Bond Cleavage ◽

Carbon Bond ◽

Carbon Carbon Bond

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ChemInform Abstract: ANGULAR DISTORTIONS AT THE CARBON BOUND TO COBALT IN COENZYME B12 MODELS. IMPLICATIONS WITH REGARD TO COBALT-CARBON BOND CLEAVAGE IN COENZYME B12 AND OTHER ALKYLCOBALAMINS

Chemischer Informationsdienst ◽

10.1002/chin.198205060 ◽

1982 ◽

Vol 13 (5) ◽

Author(s):

L. RANDACCIO ◽

N. BRESCIANI-PAHOR ◽

P. J. TOSCANO ◽

L. G. MARZILLI

Keyword(s):

Bond Cleavage ◽

Coenzyme B12 ◽

Carbon Bond

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