Formation of a cobalt-carbon bond under mild conditions. Preparation and crystal structure of an acetonyl adduct of N,N'-ethylenebis(3-fluorosalicylideniminato)cobalt(II)

William P. Schaefer; Rand Waltzman; Ben T. Huie

doi:10.1021/ja00484a025

Formation of a cobalt-carbon bond under mild conditions. Preparation and crystal structure of an acetonyl adduct of N,N'-ethylenebis(3-fluorosalicylideniminato)cobalt(II)

Journal of the American Chemical Society ◽

10.1021/ja00484a025 ◽

1978 ◽

Vol 100 (16) ◽

pp. 5063-5067 ◽

Cited By ~ 21

Author(s):

William P. Schaefer ◽

Rand Waltzman ◽

Ben T. Huie

Keyword(s):

Crystal Structure ◽

Carbon Bond ◽

Mild Conditions

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ChemInform Abstract: FORMATION OF A COBALT-CARBON BOND UNDER MILD CONDITIONS. PREPARATION AND CRYSTAL STRUCTURE OF AN ACETONYL ADDUCT OF N,N′-ETHYLENEBIS(3-FLUOROSALICYLIDENIMINATO)COBALT(II)

Chemischer Informationsdienst ◽

10.1002/chin.197846074 ◽

1978 ◽

Vol 9 (46) ◽

Author(s):

W. P. SCHAEFER ◽

R. WALTZMAN ◽

B. T. HUIE

Keyword(s):

Crystal Structure ◽

Carbon Bond ◽

Mild Conditions

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Carbon–carbon bond formation through olefin–methylcarbyne linkage at a diruthenium centre: X-ray crystal structure of [Ru2(CO)(µ-CO){µ-η1,η3-C(Me)C(Me)CH2}(η-C5H5)2]

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39810000537 ◽

1981 ◽

pp. 537-538 ◽

Cited By ~ 16

Author(s):

Andrew F. Dyke ◽

Jacques E. Guerchais ◽

Selby A. R. Knox ◽

Jean Roué ◽

Richard L. Short ◽

...

Keyword(s):

Crystal Structure ◽

Bond Formation ◽

Carbon Bond ◽

X Ray ◽

Carbon Carbon Bond

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An unusual carbon–carbon bond scission reaction with molecular oxygen under mild conditions; formation of piperidines from 1-azabicyclo[2.2.2]octanes

Journal of the Chemical Society Perkin Transactions 1 ◽

10.1039/a701223c ◽

1997 ◽

pp. 3679-3684 ◽

Cited By ~ 4

Author(s):

Timothy Norris ◽

Dinos Santafianos ◽

Jon Bordner

Keyword(s):

Molecular Oxygen ◽

Carbon Bond ◽

Mild Conditions ◽

Carbon Carbon Bond ◽

Bond Scission

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Rapid phosphorus–carbon bond cleavage in bis(diphenylphosphino)methane under very mild conditions: a one-step synthesis of µ-PPh2, µ-Ph2PCH2PPh2binuclear CoIand NiIcarbonyls directly from CoIIand NiIIsalts

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39900000032 ◽

1990 ◽

pp. 32-33 ◽

Cited By ~ 15

Author(s):

David J. Elliot ◽

David G. Holah ◽

Alan N. Hughes ◽

Hameed A. Mirza ◽

Elizabeth Zawada

Keyword(s):

Bond Cleavage ◽

Carbon Bond ◽

Mild Conditions ◽

One Step

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The Stereoisomers of 5-Bromo-6,8-dimethoxy-1,2,3-trimethyl-1,2,3,4-tetrahydroisoquinoline. X-Ray Crystal-Structure of the trans Isomer

Australian Journal of Chemistry ◽

10.1071/ch9900079 ◽

1990 ◽

Vol 43 (1) ◽

pp. 79 ◽

Cited By ~ 7

Author(s):

MA Rizzacasa ◽

MV Sargent ◽

BW Skelton ◽

AH White

Keyword(s):

Crystal Structure ◽

Single Crystal ◽

Trans Isomer ◽

Henry Reaction ◽

X Ray ◽

Mild Conditions ◽

Threo Isomer

Henry reaction between 3,5-dimethoxybenzaldehyde (2) and nitroethane gave (E)-2-(3,5-dimethoxyphenyl)-1-methyl-1-nitroethene (3). Under mild conditions the erythro and threo nitro aldols intermediate in this reaction could be isolated as their acetates. The threo isomer was obtained in diastereoisomeric excess. The nitrostyrene (3) was converted in several steps into cis-(20) and trans-5-bromo-6,8-dimethoxy-1,2,3-trimethyl-1,2,3,4-tetrahydroisoquinoline (18). The single-crystal X-ray structure of compound (18) is reported.

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Stereoselective carbon–carbon bond formation via alkylation of [(η-5C5H5)Fe(PPh3)(CO)(COMeCHR)](R = Me,Prn,Ph): X-ray crystal structure of (Z)-[(η5-C5H5)Fe(PPh3)(CO)(COMeCHMe)]

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39840000745 ◽

1984 ◽

Vol 0 (12) ◽

pp. 745-747 ◽

Cited By ~ 11

Author(s):

Gordon J. Baird ◽

Stephen G. Davies ◽

Richard H. Jones ◽

Keith Prout ◽

Peter Warner

Keyword(s):

Crystal Structure ◽

Bond Formation ◽

Carbon Bond ◽

X Ray ◽

Carbon Carbon Bond

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Synthesis of high-nuclearity carbonyl–phosphine clusters of palladium under mild conditions and X-ray crystal structure of Pd38(µ3-CO)4(µ2-CO)24(PEt3)12

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39870000218 ◽

1987 ◽

pp. 218-219 ◽

Cited By ~ 30

Author(s):

Eugenii G. Mednikov ◽

Nikolai K. Eremenko ◽

Yuri L. Slovokhotov ◽

Yuri T. Struchkov

Keyword(s):

Crystal Structure ◽

X Ray ◽

Mild Conditions

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Carbon–Carbon Bond Cleavage and Esterification of Phenylacetonitrile and its Derivatives Affording the Corresponding Benzoic Esters

Journal of Chemical Research ◽

10.3184/030823407x218110 ◽

2007 ◽

Vol 2007 (6) ◽

pp. 323-324 ◽

Cited By ~ 7

Author(s):

Zhiyuan Wang ◽

Junhui Kang ◽

Mingxin Yu

Keyword(s):

Potassium Iodide ◽

Elemental Analysis ◽

Bond Cleavage ◽

Carbon Bond ◽

H Nmr ◽

Mild Conditions ◽

Carbon Carbon Bond

Phenylacetonitrile and its derivatives were treated with alcohols in the presence of potassium iodide and iodine affording the corresponding benzoate esters via degradation, oxidation and esterification under mild conditions. The products were characterised by IR, 1H NMR, MS and elemental analysis.

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