Experimental and theoretical studies of Nin(C2H4)m. Synthesis, vibrational and electronic spectra, and generalized valence bond-configuration interaction studies. The metal atom chemistry and a localized bonding model for ethylene chemisorbed on bulk nickel

1978 ◽  
Vol 100 (15) ◽  
pp. 4750-4760 ◽  
Author(s):  
G. A. Ozin ◽  
W. J. Power ◽  
T. H. Upton ◽  
W. A. Goddard
1995 ◽  
Vol 99 (41) ◽  
pp. 14992-15003 ◽  
Author(s):  
M. M. Szostak ◽  
T. Misiaszek ◽  
S. Roszak ◽  
J. G. Rankin ◽  
R. S. Czernuszewicz

2018 ◽  
Vol 125 (1) ◽  
pp. 34-41
Author(s):  
M. S. Fedorov ◽  
N. I. Giricheva ◽  
E. A. Lapykina ◽  
M. S. Korableva

Molecules ◽  
2020 ◽  
Vol 25 (21) ◽  
pp. 4943 ◽  
Author(s):  
Lili Zhao ◽  
Chaoqun Chai ◽  
Wolfgang Petz ◽  
Gernot Frenking

This review summarizes experimental and theoretical studies of transition metal complexes with two types of novel metal-carbon bonds. One type features complexes with carbones CL2 as ligands, where the carbon(0) atom has two electron lone pairs which engage in double (σ and π) donation to the metal atom [M]⇇CL2. The second part of this review reports complexes which have a neutral carbon atom C as ligand. Carbido complexes with naked carbon atoms may be considered as endpoint of the series [M]-CR3 → [M]-CR2 → [M]-CR → [M]-C. This review includes some work on uranium and cerium complexes, but it does not present a complete coverage of actinide and lanthanide complexes with carbone or carbide ligands.


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