Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins

David E. Van Horn; Eiichi Negishi

doi:10.1021/ja00475a058

Selective carbon-carbon bond formation via transition metal catalysts. 8. Controlled carbometalation. Reaction of acetylenes with organoalane-zirconocene dichloride complexes as a route to stereo- and regio-defined trisubstituted olefins

Journal of the American Chemical Society ◽

10.1021/ja00475a058 ◽

1978 ◽

Vol 100 (7) ◽

pp. 2252-2254 ◽

Cited By ~ 192

Author(s):

David E. Van Horn ◽

Eiichi Negishi

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Metal Catalysts ◽

Transition Metal Catalysts ◽

Carbon Bond ◽

Zirconocene Dichloride ◽

Carbon Carbon Bond ◽

Trisubstituted Olefins

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ChemInform Abstract: SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSTS. 8. CONTROLLED CARBOMETALATION. REACTION OF ACETYLENES WITH ORGANOALANE-ZIRCONOCENE DICHLORIDE COMPLEXES AS A ROUTE TO STEREO- AND REGIO-DEFINED TRISUBSTITUTED OLEF

Chemischer Informationsdienst ◽

10.1002/chin.197829182 ◽

1978 ◽

Vol 9 (29) ◽

Author(s):

D. E. VAN HORN ◽

E. NEGISHI

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Metal Catalysts ◽

Transition Metal Catalysts ◽

Carbon Bond ◽

Zirconocene Dichloride ◽

Carbon Carbon Bond

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Selective carbon-carbon bond formation via transition metal catalysts. 9. Double metal catalysis in the cross-coupling reaction and its application to the stereo- and regioselective synthesis of trisubstituted olefins

Journal of the American Chemical Society ◽

10.1021/ja00475a059 ◽

1978 ◽

Vol 100 (7) ◽

pp. 2254-2256 ◽

Cited By ~ 231

Author(s):

Eiichi Negishi ◽

Nobuhisa Okukado ◽

Anthony O. King ◽

David E. Van Horn ◽

Barry I. Spiegel

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Coupling Reaction ◽

Cross Coupling ◽

Transition Metal Catalysts ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Cross Coupling Reaction ◽

Trisubstituted Olefins

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Carbon-Carbon Bond Formation in a Weak Ligand Field: Leveraging Open-Shell First-Row Transition-Metal Catalysts

Angewandte Chemie International Edition ◽

10.1002/anie.201611959 ◽

2017 ◽

Vol 56 (19) ◽

pp. 5170-5181 ◽

Cited By ~ 76

Author(s):

Paul J. Chirik

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Open Shell ◽

Metal Catalysts ◽

Transition Metal Catalysts ◽

Ligand Field ◽

Carbon Bond ◽

Carbon Carbon Bond

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ChemInform Abstract: SELECTIVE CARBON-CARBON BOND FORMATION VIA TRANSITION METAL CATALYSTS. 9. DOUBLE METAL CATALYSIS IN THE CROSS-COUPLING REACTION AND ITS APPLICATION TO THE STEREO- AND REGIOSELECTIVE SYNTHESIS OF TRISUBSTITUTED OLEFINS

Chemischer Informationsdienst ◽

10.1002/chin.197829183 ◽

1978 ◽

Vol 9 (29) ◽

Author(s):

E. NEGISHI ◽

N. OKUKADO ◽

A. O. KING ◽

D. E. VAN HORN ◽

B. I. SPIEGEL

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Coupling Reaction ◽

Cross Coupling ◽

Transition Metal Catalysts ◽

Metal Catalysis ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Cross Coupling Reaction ◽

Trisubstituted Olefins

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Selective, Catalytic Carbon—Carbon Bond Activation and Functionalization Promoted by Late Transition Metal Catalysts.

ChemInform ◽

10.1002/chin.200322074 ◽

2003 ◽

Vol 34 (22) ◽

Author(s):

Suzanne C. Bart ◽

Paul J. Chirik

Keyword(s):

Transition Metal ◽

Bond Activation ◽

Metal Catalysts ◽

Transition Metal Catalysts ◽

Late Transition Metal ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Late Transition

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Chelation-Assisted Carbon–Hydrogen and Carbon–Carbon Bond Activation by Transition Metal Catalysts

Chemistry - A European Journal ◽

10.1002/1521-3765(20020603)8:11<2422::aid-chem2422>3.0.co;2-b ◽

2002 ◽

Vol 8 (11) ◽

pp. 2422 ◽

Cited By ~ 103

Author(s):

Chul-Ho Jun ◽

Choong Woon Moon ◽

Dae-Yon Lee

Keyword(s):

Transition Metal ◽

Bond Activation ◽

Metal Catalysts ◽

Transition Metal Catalysts ◽

Carbon Bond ◽

Carbon Carbon Bond

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ChemInform Abstract: Carbon Dioxide as a Carbon Source in Organic Transformation: Carbon-Carbon Bond Forming Reactions by Transition-Metal Catalysts

ChemInform ◽

10.1002/chin.201250235 ◽

2012 ◽

Vol 43 (50) ◽

pp. no-no

Author(s):

Yasushi Tsuji ◽

Tetsuaki Fujihara

Keyword(s):

Carbon Dioxide ◽

Carbon Source ◽

Transition Metal ◽

Metal Catalysts ◽

Transition Metal Catalysts ◽

Carbon Bond ◽

Bond Forming ◽

Carbon Carbon Bond ◽

Bond Forming Reactions

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Selective, Catalytic Carbon−Carbon Bond Activation and Functionalization Promoted by Late Transition Metal Catalysts

Journal of the American Chemical Society ◽

10.1021/ja028912j ◽

2003 ◽

Vol 125 (4) ◽

pp. 886-887 ◽

Cited By ~ 110

Author(s):

Suzanne C. Bart ◽

Paul J. Chirik

Keyword(s):

Transition Metal ◽

Bond Activation ◽

Metal Catalysts ◽

Transition Metal Catalysts ◽

Late Transition Metal ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Late Transition

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New approaches to high-activity transition-metal catalysts for carbon–carbon bond forming reactions. Rhenium-containing phosphorus donor ligands for palladium-catalyzed Suzuki cross-couplings

Chemical Communications ◽

10.1039/b201512a ◽

2002 ◽

pp. 1046-1047 ◽

Cited By ~ 7

Author(s):

Sandra Eichenseher ◽

Klemenz Kromm ◽

Olivier Delacroix ◽

J. A. Gladysz

Keyword(s):

Transition Metal ◽

High Activity ◽

Metal Catalysts ◽

Transition Metal Catalysts ◽

Donor Ligands ◽

Carbon Bond ◽

Bond Forming ◽

New Approaches ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

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ChemInform Abstract: New Approaches to High-Activity Transition-Metal Catalysts for Carbon-Carbon Bond Forming Reactions. Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catalyzed Suzuki Cross-Couplings.

ChemInform ◽

10.1002/chin.200237060 ◽

2010 ◽

Vol 33 (37) ◽

pp. no-no

Author(s):

Sandra Eichenseher ◽

Klemenz Kromm ◽

Olivier Delacroix ◽

J. A. Gladysz

Keyword(s):

Transition Metal ◽

High Activity ◽

Metal Catalysts ◽

Transition Metal Catalysts ◽

Donor Ligands ◽

Carbon Bond ◽

Bond Forming ◽

New Approaches ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

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