The role of distance in electron transfer in solution. Experimental verification of the Hush-Marcus theory using mixed-valence complexes

1976 ◽  
Vol 98 (21) ◽  
pp. 6731-6733 ◽  
Author(s):  
Michael J. Powers ◽  
Dennis J. Salmon ◽  
Robert W. Callahan ◽  
Thomas J. Meyer
Keyword(s):  
Electron Transfer ◽  
Experimental Verification ◽  
Mixed Valence ◽  
Marcus Theory

Role of the Electron Transfer and Magnetic Exchange Interactions in the Magnetic Properties of Mixed-Valence Polyoxovanadate Complexes

2008 ◽  
Vol 47 (13) ◽  
pp. 5889-5901 ◽  
Author(s):  
Carmen J. Calzado ◽  
Juan M. Clemente-Juan ◽  
Eugenio Coronado ◽  
Alejandro Gaita-Arino ◽  
Nicolas Suaud
Keyword(s):  
Electron Transfer ◽  
Magnetic Properties ◽  
Mixed Valence ◽  
Exchange Interactions ◽  
Magnetic Exchange

CAN QUANTUM PROCESSES CONTROL SYNAPTIC EMISSION?

1996 ◽  
Vol 07 (04) ◽  
pp. 343-353 ◽  
Author(s):  
FRIEDRICH BECK
Keyword(s):  
Electron Transfer ◽  
Protein Complexes ◽  
Brain Activity ◽  
Synaptic Cleft ◽  
Thermal Fluctuations ◽  
Scientific Basis ◽  
Marcus Theory ◽  
Quantum Processes ◽  
Emission Process

The role of quantum processes in brain activity has been discussed intensively in recent years. Some authors regard the indeterminacy of quantum events as key property to relate brain activity and consciousness on a scientific basis. Here we ask the question where quantum events could be effective in the complex cortical structure. We argue that only elementary microscopic processes like electron transfer in protein complexes are able to survive thermal fluctuations. A model for the quantal emission process at the synaptic cleft is presented and related to the mechanism of electron transfer between different molecular states, as described by Marcus theory.

Electron transfer in tetranuclear mixed-valence iron clusters. Role of the topology on the magnetic properties

1992 ◽  
Vol 166 (1-2) ◽  
pp. 139-144 ◽  
Author(s):  
J.J. Borras-Almenar ◽  
E. Coronado ◽  
R. Georges ◽  
C.J. Gomez-Garcia
Keyword(s):  
Electron Transfer ◽  
Magnetic Properties ◽  
Mixed Valence ◽  
Iron Clusters

scholarly journals Conversion of Methanol on Rutile TiO2 (110) and Tungsten Oxide Clusters: 2. The Role of Defects and Electron Transfer in Bifunctional Oxidic Photocatalysts

2021 ◽  
Author(s):  
Lars Mohrhusen ◽  
Jessica Kräuter ◽  
Katharina Al-Shamery
Keyword(s):  
Electron Transfer ◽  
Transition Metal ◽  
Metal Oxide ◽  
Tungsten Oxide ◽  
Organic Compounds ◽  
Uv Irradiation ◽  
Organic P ◽  
Rutile Tio2 ◽  
Metal Oxide Surfaces

The photochemical conversion of organic compounds on tailored transition metal oxide surfaces by (UV) irradiation has found wide applications ranging from the production of chemicals to the degradation of organic...

Improving peroxymonosulfate activation by copper ion-saturated adsorbent-based single atom catalysts for the degradation of organic contaminants: electron-transfer mechanism and the key role of Cu single atoms

2021 ◽  
Author(s):  
Jingwen Pan ◽  
Baoyu Gao ◽  
Pijun Duan ◽  
Kangying Guo ◽  
Muhammad Akram ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Organic Contaminants ◽  
High Salinity ◽  
Copper Ion ◽  
Single Atom ◽  
Electron Transfer Mechanism ◽  
Persulfate Oxidation ◽  
Single Atoms ◽  
Oxidation Technology

Nonradical pathway-based persulfate oxidation technology is considered to be a promising method for high-salinity organic wastewater treatment.

scholarly journals On the role of non-diagonal system–environment interactions in bridge-mediated electron transfer

2020 ◽  
Vol 153 (18) ◽  
pp. 185101
Author(s):  
Nirmalendu Acharyya ◽  
Roman Ovcharenko ◽  
Benjamin P. Fingerhut
Keyword(s):  
Electron Transfer ◽  
System Environment ◽  
Diagonal System ◽  
Mediated Electron Transfer
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