Aromatic substitution. XXXVII. Stannic and aluminum chloride catalyzed Friedel-Crafts alkylation of naphthalene with alkyl halides. Differentiation of kinetically and thermodynamically controlled product compositions, and the isomerization of alkylnaphthalenes

1976 ◽  
Vol 98 (7) ◽  
pp. 1839-1842 ◽  
Author(s):  
George A. Olah ◽  
Judith A. Olah
Keyword(s):  
Aluminum Chloride ◽  
Alkyl Halides ◽  
Aromatic Substitution

Nucleophile/Electrophile Combinations in Aromatic Substitution: From Wheland to Wheland–Meisenheimer Intermediates Using Strongly Activated Arenes

Synthesis ◽  
2017 ◽  
Vol 49 (15) ◽  
pp. 3347-3356 ◽  
Author(s):  
Gabriele Micheletti ◽  
Carla Boga
Keyword(s):  
Nitrogen Atom ◽  
Carbon Atom ◽  
Short Review ◽  
Alkyl Halides ◽  
Aryl Halides ◽  
Aromatic Substitution ◽  
Aromatic Carbon ◽  
Isolation And Characterization ◽  
Acyl Halides

This short review provides an overview on the interaction between 1,3,5-triaminobenzene derivatives and different kinds of electrophiles. Due to the ambident reactivity of these nucleophiles (i.e., at the nitrogen atom of the substituents and at the aromatic carbon atom) different compounds can be obtained. Particular attention is devoted to the detection, isolation, and characterization of covalent intermediates of aromatic substitution, starting from Wheland intermediates until the first detection and characterization of Wheland–Meisenheimer intermediates.1 Introduction2 Reactions between 1,3,5-Triaminobenzene Derivatives and Charged Electrophiles2.1 The Proton as an Electrophile2.2 Arenediazonium Salts as Electrophiles3 Reactions between 1,3,5-Triaminobenzene Derivatives and Neutral­ Electrophiles3.1 Alkyl Halides as Electrophiles3.2 Acyl Halides and Sulfonyl Chlorides as Electrophiles3.3 Aryl Halides and Heteroaryl Halides as Electrophiles3.4 Polynitroheteroaromatics as Electrophiles4 Conclusion

A New Method of Aromatic Substitution Yielding Unusual Orientation. Amination with N-Haloamines Catalyzed by Aluminum Chloride

1964 ◽  
Vol 86 (8) ◽  
pp. 1650-1651 ◽  
Author(s):  
Peter. Kovacic ◽  
Richard M. Lange ◽  
J. Lindsley. Foote ◽  
Christian T. Goralski ◽  
John J. Hiller ◽  
...  
Keyword(s):  
Aluminum Chloride ◽  
New Method ◽  
Aromatic Substitution

Aluminum Chloride–Iron Promoted Coupling of Sulfonyl Chlorides with Alkyl Halides in Aqueous Media

2001 ◽  
Vol 30 (6) ◽  
pp. 512-513 ◽  
Author(s):  
Promod Saikia ◽  
Dhrubojyoti D. Laskar ◽  
Dipak Prajapati ◽  
Jagir S. Sandhu
Keyword(s):  
Aluminum Chloride ◽  
Aqueous Media ◽  
Alkyl Halides ◽  
Sulfonyl Chlorides
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