Aluminum-27 nuclear magnetic resonance study of the room-temperature melt aluminum trichloride butylpyridinium chloride

1981 ◽  
Vol 103 (24) ◽  
pp. 7147-7151 ◽  
Author(s):  
Joel L. Gray ◽  
Gary E. Maciel
1985 ◽  
Vol 63 (7) ◽  
pp. 946-950 ◽  
Author(s):  
Nam Doo Moon ◽  
Kyunghee Lee ◽  
Sung Ho Choh

The nuclear magnetic resonance of 1H in Rb2CuCl4∙2H2O and isomorphic Rb2CuBr4∙2H2O has been measured at room temperature, near 165, and 77 K. The fractional spin transfer from the copper ion to hydrogen due to the transferred hyperfine interaction is analyzed: 0.22 ± 0.03% at 300 K, 0.25 ± 0.02% at 168 K, and 0.29 ± 0.02% at 77 K in Rb2CuCl4∙2H2O; and 0.22 ± 0.03% at 300 K, 0.28 ± 0.02% at 163 K, and 0.32 ± 0.02% at 77 K in Rb2CuBr4∙2H2O. The temperature-dependent spin transfers are discussed in terms of the molecular mass and the bond strength of the two compounds.


1999 ◽  
Vol 11 (3) ◽  
pp. 871-879 ◽  
Author(s):  
A Taye ◽  
G Klotzsche ◽  
D Michel ◽  
S Mulla-Osman ◽  
R Böttcher

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