Calorimetric study of the oxidative addition of acyl chlorides to iridium(I) complexes in solution, the standard state and the gas phase

1981 ◽  
Vol 103 (19) ◽  
pp. 5768-5771 ◽  
Author(s):  
Gerald Yoneda ◽  
Szu-Min Lin ◽  
Lou-Pin Wang ◽  
Daniel M. Blake
Keyword(s):  
Gas Phase ◽  
Oxidative Addition ◽  
Calorimetric Study ◽  
Standard State ◽  
Acyl Chlorides

The sorption of krypton and xenon in zeolites at high pressures and temperatures I. Chabazite

1972 ◽  
Vol 326 (1566) ◽  
pp. 315-330 ◽  
Keyword(s):  
Gas Phase ◽  
Thermodynamic Equilibrium ◽  
High Pressures ◽  
Equilibrium Constants ◽  
Standard State ◽  
Temperature Range ◽  
Thermodynamic Relationship ◽  
High Pressures And Temperatures

Isotherms of Kr and Xe in chabazite have been obtained for absolute sorption and for Gibbs excess sorption, in the temperature range 150 to 450 °C and at pressures up to 100 atm. Thermodynamic equilibrium constants for distribution of gas between the crystals and the gas phase, standard state concentrations and heats of sorption have been determined. At the highest pressures differences between absolute sorption and Gibbs excess sorption were large. The change of equilibrium fugacity with temperature for given absolute and Gibbs excess sorptions yielded two differential heats of sorption and two differential entropies of the sorbate. These heats, and the corresponding entropies, differed numerically and in their dependence upon amount sorbed. The thermodynamic relationship between the two heats has been derived and discussed.

Oxidative Addition of CH3I to Au– in the Gas Phase

2016 ◽  
Vol 120 (7) ◽  
pp. 957-963 ◽  
Author(s):  
Satoru Muramatsu ◽  
Kiichirou Koyasu ◽  
Tatsuya Tsukuda
Keyword(s):  
Gas Phase ◽  
Oxidative Addition
Sign in / Sign up

Export Citation Format

Share Document