Degenerate thermal rearrangement of 1,3-dimethylenecyclopentane. Evidence for partially stereospecific biradical formation and closure in a 1,3 shift

Joseph J. Gajewski; Jose Del C. Salazar

doi:10.1021/ja00404a028

Degenerate thermal rearrangement of 1,3-dimethylenecyclopentane. Evidence for partially stereospecific biradical formation and closure in a 1,3 shift

Journal of the American Chemical Society ◽

10.1021/ja00404a028 ◽

1981 ◽

Vol 103 (14) ◽

pp. 4145-4154 ◽

Cited By ~ 12

Author(s):

Joseph J. Gajewski ◽

Jose Del C. Salazar

Keyword(s):

Thermal Rearrangement

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Synthesis of 8-phenyl substituted 3-benzazecines with allene moiety, their thermal rearrangement and evaluation as acetylcholinesterase inhibitors

Molecular Diversity ◽

10.1007/s11030-021-10185-8 ◽

2021 ◽

Author(s):

Maxim S. Kobzev ◽

Alexander A. Titov ◽

Elena V. Alexandrova ◽

Rosa Purgatorio ◽

Marco Catto ◽

...

Keyword(s):

Acetylcholinesterase Inhibitors ◽

Thermal Rearrangement

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The kinetics and thermochemistry of the thermal rearrangement of hexamethylbicyclo[2.2.0]hexa-2,5-diene (hexamethyldewarbenzene) and of hexamethyltetracyclo[2.2.0,02,6 .03,5 ]hexane (hexamethylprismane)

Recueil des Travaux Chimiques des Pays-Bas ◽

10.1002/recl.19680871012 ◽

1968 ◽

Vol 87 (10) ◽

pp. 1185-1195 ◽

Cited By ~ 36

Author(s):

Jean F. M. Oth

Keyword(s):

Thermal Rearrangement

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ChemInform Abstract: Synthesis of Functionalized Bicyclo(3.2.1)octa-2,6-dienes by Thermal Rearrangement of Substituted 6-exo-(1-Alkenyl)bicyclo(3.1.0)hex-2-ene Systems.

ChemInform ◽

10.1002/chin.198739080 ◽

1987 ◽

Vol 18 (39) ◽

Author(s):

E. PIERS ◽

G. L. JUNG ◽

E. H. RUEDIGER

Keyword(s):

Thermal Rearrangement

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Photosensitized Oxidation of Furans. 20.1A Novel Thermal Rearrangement of Suitably Substituted Alkoxyfuran Endoperoxides via Neighboring-Group Mechanism: Synthesis and Reactivity of the First Functionalized 2-Oxetanyl Hydroperoxides

The Journal of Organic Chemistry ◽

10.1021/jo0102112 ◽

2001 ◽

Vol 66 (13) ◽

pp. 4732-4735 ◽

Cited By ~ 12

Author(s):

M. R. Iesce ◽

F. Cermola ◽

F. De Lorenzo ◽

I. Orabona ◽

M. L. Graziano

Keyword(s):

Thermal Rearrangement ◽

Mechanism Synthesis ◽

Neighboring Group ◽

Photosensitized Oxidation

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Reactions of co-ordinated ligands. Part 37. Synthesis and structure of the dimolybdenum µ-allylidene complex [Mo2(µ-σ:η3-CHCHCMe2)(CO)4(η-C5H5)2]; formation and crystal structure of the oxo-µ-allylidene complex [Mo2O(µ-σ:η3-CHCHCMe2)(µ-CO)(CO)(η-C5H5)2]. Thermal rearrangement to alkyne and 1,3-diene dimolybdenum species and structure of [Mo3(µ3-η4-CCHCMeCH)(CO)4(η-C5H5)3]

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9860001021 ◽

1986 ◽

pp. 1021-1030 ◽

Cited By ~ 9

Author(s):

W. Eammon Carroll ◽

Michael Green ◽

A. Guy Orpen ◽

Colin J. Schaverien ◽

Ian D. Williams ◽

...

Keyword(s):

Crystal Structure ◽

Thermal Rearrangement

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Thermal rearrangement of 2-chloro-1-(chloromethyl)ethyl acetate

Journal of the Chemical Society Chemical Communications ◽

10.1039/c3973000269a ◽

1973 ◽

pp. 269a ◽

Cited By ~ 4

Author(s):

R. Garth Pews ◽

Ralph A. Davis

Keyword(s):

Ethyl Acetate ◽

Thermal Rearrangement

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ChemInform Abstract: A Facile Synthesis of 3-Chloro-2-oxoalkanoates (IV) via Thermal Rearrangement of 2-Chloro-2,3-epoxyalkanoates (III) Promoted by Alumina.

ChemInform ◽

10.1002/chin.198732138 ◽

1987 ◽

Vol 18 (32) ◽

Author(s):

S. TSUBOI ◽

H. FURUTANI ◽

A. TAKEDA

Keyword(s):

Thermal Rearrangement ◽

Facile Synthesis

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Thermal rearrangement of some [1.1.1] propellanes

Tetrahedron Letters ◽

10.1016/s0040-4039(00)85341-1 ◽

1986 ◽

Vol 27 (48) ◽

pp. 5839-5842 ◽

Cited By ~ 21

Author(s):

Johannes Belzner ◽

Gunter Szeimies

Keyword(s):

Thermal Rearrangement

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Thermal Rearrangement of Cyanurates in the Solid State

Molecular Crystals and Liquid Crystals Science and Technology Section A Molecular Crystals and Liquid Crystals ◽

10.1080/10587259408029735 ◽

1994 ◽

Vol 240 (1) ◽

pp. 241-249 ◽

Cited By ~ 3

Author(s):

Menahem Kaftory ◽

Edit Handelsman-Benory

Keyword(s):

Solid State ◽

Thermal Rearrangement

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Stereodivergent Synthesis of β-Lactams Using Thermal Rearrangement of Aminocyclobutenones

Organic Letters ◽

10.1021/ol901192y ◽

2009 ◽

Vol 11 (15) ◽

pp. 3266-3268 ◽

Cited By ~ 26

Author(s):

Iwao Hachiya ◽

Takuya Yoshitomi ◽

Yukari Yamaguchi ◽

Makoto Shimizu

Keyword(s):

Thermal Rearrangement

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