A free-radical chain reaction involving electron transfer. The replacement of the nitro group by hydrogen using trialkyltin hydride, a variation of the Kornblum reaction

1981 ◽  
Vol 103 (6) ◽  
pp. 1557-1559 ◽  
Author(s):  
Dennis D. Tanner ◽  
Edward V. Blackburn ◽  
Gilberto E. Diaz
Keyword(s):  
Electron Transfer ◽  
Free Radical ◽  
Nitro Group ◽  
Chain Reaction ◽  
Radical Chain ◽  
Kornblum Reaction ◽  
Free Radical Chain Reaction ◽  
Radical Chain Reaction

The reaction of thionitrites with barton esters: a convenient free radical chain reaction for decarboxylative nitrosation

Tetrahedron ◽  
1999 ◽  
Vol 55 (12) ◽  
pp. 3573-3584 ◽  
Author(s):  
Pierre Girard ◽  
Nadine Guillot ◽  
William B. Motherwell ◽  
Robyn S. Hay-Motherwell ◽  
Pierre Potier
Keyword(s):  
Free Radical ◽  
Chain Reaction ◽  
Radical Chain ◽  
Free Radical Chain Reaction ◽  
Radical Chain Reaction

Rubber, Polyisoprenes, and Allied Compounds. VII. Action of Nitric Oxide

1944 ◽  
Vol 17 (4) ◽  
pp. 772-778
Author(s):  
George F. Bloomfield ◽  
G. A. Jeffrey
Keyword(s):  
Nitric Oxide ◽  
Free Radical ◽  
Reaction Mechanism ◽  
Nitro Compounds ◽  
Chain Reaction ◽  
Considerable Part ◽  
Radical Chain ◽  
Ethylenic Carbon ◽  
Free Radical Chain Reaction ◽  
Radical Chain Reaction

Abstract The reaction of nitric oxide with the olefins cyclohexene, 1-methylcyclohexene, dihydromyrcene, and rubber presents characteristics of a free-radical, chain reaction. In the products, the molecular ratio of combined oxygen to nitrogen is considerably in excess of 1:1, the nitrogen atom being generally directly linked to carbon. In many instances definite nitro compounds have been isolated, and a considerable part of the attack appears to proceed at the ethylenic carbon atoms, either by substitution or addition of NO2 and N2O3 groups. The precise reaction mechanism is obscure.

Sign in / Sign up

Export Citation Format

Share Document