Absolute rate constants for the reaction of triethylsilyl radicals with organic halides

1982 ◽  
Vol 104 (19) ◽  
pp. 5123-5127 ◽  
Author(s):  
C. Chatgilialoglu ◽  
K. U. Ingold ◽  
J. C. Scaiano
Keyword(s):  
Rate Constants ◽  
Absolute Rate ◽  
Organic Halides

ChemInform Abstract: ABSOLUTE RATE CONSTANTS FOR REACTIONS OF PHENYL RADICALS

1978 ◽  
Vol 9 (20) ◽  
Author(s):  
V. MADHAVAN ◽  
R. H. SCHULER ◽  
R. W. FESSENDEN
Keyword(s):  
Rate Constants ◽  
Absolute Rate ◽  
Phenyl Radicals

Reactions of the hydroxyl radical. Part 2.—Determination of absolute rate constants

1965 ◽  
Vol 61 (0) ◽  
pp. 1417-1424 ◽  
Author(s):  
G. E. Adams ◽  
J. W. Boag ◽  
B. D. Michael
Keyword(s):  
Hydroxyl Radical ◽  
Rate Constants ◽  
Absolute Rate

Absolute Rate Constants for Hydrocarbon Autoxidation. Part XX. Oxidation of Some Organic Sulfides

1971 ◽  
Vol 49 (12) ◽  
pp. 2178-2182 ◽  
Author(s):  
J. A. Howard ◽  
S. Korcek
Keyword(s):  
Liquid Phase ◽  
Hydrogen Atom ◽  
Rate Constants ◽  
Hydrogen Atom Abstraction ◽  
Absolute Rate ◽  
Organic Sulfides

Absolute rate constants for the liquid phase autoxidation of some organic sulfides at 30 °C have been measured. The reactivities of organic sulfides towards t-butylperoxy radicals are equal to or somewhat less than the reactivities of structurally analogous ethers. The α-alkylthiylalkylperoxy radicals appear to be about 3–5 times more reactive in hydrogen atom abstraction than the α-alkoxyalkylperoxy radicals.

An electron spin resonance study of the reactions of hydrogen atoms with halocarbons

1986 ◽  
Vol 64 (11) ◽  
pp. 2192-2195 ◽  
Author(s):  
William E. Jones ◽  
Joseph L. Ma
Keyword(s):  
Rate Constants ◽  
Gas Flow ◽  
Esr Spectroscopy ◽  
Flow System ◽  
Electron Spin Resonance Study ◽  
Absolute Rate ◽  
Hydrogen Atoms ◽  
Vinyl Halides ◽  
Spin Resonance ◽  
Spin Resonance Study

The absolute rate constants for the reaction of H atoms with methyl- and vinyl-halides have been determined using esr spectroscopy and a conventional gas flow system. The rate constants determined at 298 ± 2 K at a pressure of 0.55 Torr are methane, (1.7 ± 0.3) × 10−17; ethane, (2.3 ± 0.5) × 10−17; methylfluoride, (4 ± 3) × 10−15; methylchloride, (8 ± 2) × 10−16; methylbromide, (2.1 ± 0.6) × 10−14; vinylfluoride, (1.47 ± 0.02) × 10−13; vinylchloride, (1.66 ± 0.08) × 10−13; and vinylbromide (4.07 ± 0.73) × 10−13 in units of cm3 molecule−1 s−1.

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