Mercury(1+) (6s1) ions in potassium dihydrogen phosphate and ammonium dihydrogen phosphate: new paramagnetic probes of cationic dynamics near phase transitions in hydrogen-bonded ferroelectrics and antiferroelectrics

1982 ◽  
Vol 104 (7) ◽  
pp. 2054-2056 ◽  
Author(s):  
N. S. Dalal ◽  
D. Nettar ◽  
P. Grandinetti
Keyword(s):  
Phase Transitions ◽  
Potassium Dihydrogen Phosphate ◽  
Dihydrogen Phosphate ◽  
Ammonium Dihydrogen Phosphate ◽  
Potassium Dihydrogen ◽  
Paramagnetic Probes ◽  
Hydrogen Bonded

The Effect of Phosphatic Composite on Magnesium Phosphate Cement Performance

2014 ◽  
Vol 809-810 ◽  
pp. 477-484
Author(s):  
Zhao Qing Qi ◽  
Hong Tao Wang ◽  
Jun Liang Dang ◽  
Shi Hao Zhang ◽  
Jian Hua Ding
Keyword(s):  
Setting Time ◽  
Potassium Dihydrogen Phosphate ◽  
Magnesium Phosphate ◽  
Dihydrogen Phosphate ◽  
Ammonium Dihydrogen Phosphate ◽  
Hydrogen Phosphate ◽  
Sodium Dihydrogen Phosphate ◽  
Disodium Hydrogen Phosphate ◽  
Potassium Dihydrogen ◽  
Sodium Dihydrogen

The capacity of 10%, 30%, and 50% ammonium dihydrogen phosphate were replaced with an equal amount of three phosphate (potassium dihydrogen phosphate, sodium dihydrogen phosphate, disodium hydrogen phosphate) respectively. Magnesium phosphate cement was made by phosphate of replaced, which strength, setting time, fluidity, hydration temperature, and the hydration products was researched. The results show that: MPC was made that replaced with the equal amount of three kind of phosphate, which has good mechanical properties. Setting time and fluidity change along with the replacment. Three kind of phosphate replace ammonium dihydrogen phosphate, which change the hydration process of MPC. When ammonium dihydrogen phosphate was replaced by an equal amount of disodium hydrogen phosphate, the temperature of hydration is only 69.4 °C. XRD showed that the diffraction peaks of composite’s magnesium phosphate cement increases.

scholarly journals KH2PO4 crystallisation from potassium chloride and ammonium dihydrogen phosphate

2016 ◽  
Vol 18 (1) ◽  
pp. 1-8 ◽  
Author(s):  
Kristina Jančaitienė ◽  
Rasa Šlinkšienė
Keyword(s):  
Aqueous Solutions ◽  
Potassium Chloride ◽  
Solid Phase ◽  
Potassium Dihydrogen Phosphate ◽  
Molar Ratio ◽  
Dihydrogen Phosphate ◽  
Ammonium Dihydrogen Phosphate ◽  
Potassium Dihydrogen ◽  
Increasing Temperature ◽  
Nitrogen Phosphorus

Abstract Seeking to obtain bulk (NPK – nitrogen, phosphorus, potassium), chlorine-free fertilizers, the influence of interaction between potassium chloride and ammonium dihydrogen phosphate in aqueous solutions at temperature of 20, 40, 60 and 80°C has been investigated. Components of the solid phase have been identified by methods of chemical and instrumental analysis: radiography (X – ray), infra – red molecular absorption spectroscopy (IR) and scanning electron microscopy (SEM). It has been observed that the largest amount of solid state potassium dihydrogen phosphate was obtained at 60–80°C, when the potassium chloride and ammonium dihydrogen phosphate molar ratio is equal 0.8:0.2. Changing the molar ratio of 0.5:0.5 to 0.8:0.2, and with increasing temperature, various shaped crystals have developed in the remaining aqueous solutions with a morphology shifting from sharp needles to tetragonal prism.

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