Twisted carbon-carbon double bonds. Crystal and molecular structure of 4,5-di-tert-butyl-1,1,2,2-tetrafluoro-1,2-disilacyclohexa-3,5-diene

1982 ◽  
Vol 104 (6) ◽  
pp. 1594-1598 ◽  
Author(s):  
Tzong Hsiung Hseu ◽  
Yun Chi ◽  
Chao Shiuan Liu
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Double Bonds ◽  
Tert Butyl

Chrom(0)-und Molybdän(0)-Komplexe von 11-Isopropyliden-bicyclo[4.4.1]undeca-2,4,8-trienen / Chromium(0) and Molybdenum(0) Complexes of 11-Isopropylidene-bicyclo[4.4. 1]undeca-2,4,8-trienes

1986 ◽  
Vol 41 (6) ◽  
pp. 722-730 ◽  
Author(s):  
Cornelius G. Kreiter ◽  
Eduard Michels ◽  
Jürgen Kaub
Keyword(s):  
Molecular Structure ◽  
Double Bond ◽  
Nmr Spectroscopy ◽  
Transition Metals ◽  
Crystal And Molecular Structure ◽  
Double Bonds ◽  
Conjugated Diene ◽  
X Ray ◽  
Ir And Nmr Spectroscopy ◽  
Elemental Analyses

11-Isopropylidene-bicyclo[4.4.1]undeca-2,4,8-triene (IBU, 1A) and five alkyl substituted de­rivatives (1B-1F) contain a conjugated diene unit and two isolated CC-double bonds, one exocyclic and one incorporated into the bicvclus, each suited for complexation to transition metals. With [Cr(CO)3(CH3CN)3] (2) 1A-1F form [Cr(CO)3(η6-IBU)] complexes (3A−3F). in which the IBU ligands are coordinated to the chromium via the diene unit and the exocyclic CC-double bond. The corresponding [Mo(CO)3(η6-IBU)] complexes (5A−5F) are obtained from the reactions of [Mo(CO)3(diglyme)] (4) with 1A−1F. In addition, the isomeric [Mo(CO)3(η6-IBU)] complexes (6A−6D) are formed, in which the IBU ligands are bound to molybdenum via the three cyclic CC-double bonds. The complexes 3A−3F, 5A−5F and 6A−6D were studied by IR and NMR spectroscopy (1H. 13C) and characterized by C, H elemental analyses. The crystal and molecular structure of 1A was determined by X-ray structure analysis.

Crystal and molecular structure of tris(tert-butyl thioxanthato)iron(III)

1972 ◽  
Vol 11 (4) ◽  
pp. 823-828 ◽  
Author(s):  
D. F. Lewis ◽  
S. J. Lippard ◽  
J. A. Zubieta
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Tert Butyl
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