Olefin metathesis - a mechanistic study of high-valent Group VI catalysts

1982 ◽  
Vol 104 (2) ◽  
pp. 448-456 ◽  
Author(s):  
Anthony K. Rappe ◽  
William A. Goddard
Keyword(s):  
Olefin Metathesis ◽  
Mechanistic Study ◽  
Group Vi ◽  
High Valent

Nitrenium ions and trivalent boron ligands as analogues of N-heterocyclic carbenes in olefin metathesis: a computational study

2015 ◽  
Vol 44 (46) ◽  
pp. 20021-20026 ◽  
Author(s):  
A. Pazio ◽  
K. Woźniak ◽  
K. Grela ◽  
B. Trzaskowski
Keyword(s):  
Olefin Metathesis ◽  
Computational Study ◽  
Heterocyclic Carbenes ◽  
Mechanistic Study ◽  
Nitrenium Ions ◽  
Nitrenium Ion ◽  
Metathesis Catalysts

A DFT mechanistic study reveals that nitrenium ion-modified Hoveyda-like complexes are good candidates for latent metathesis catalysts, while boron-modified systems are candidates for very fast metathesis catalysts.

Hydrocarbon oxidation by high-valent Group VI oxides

1982 ◽  
Vol 104 (12) ◽  
pp. 3287-3294 ◽  
Author(s):  
Anthony K. Rappe ◽  
William A. Goddard
Keyword(s):  
Hydrocarbon Oxidation ◽  
Group Vi ◽  
High Valent

scholarly journals Olefin Metathesis by Group VI (Mo, W) Metal Compounds

Alkenes ◽  
2018 ◽  
Author(s):  
Frédéric Lefebvre ◽  
Yassine Bouhoute ◽  
Kai C. Szeto ◽  
Nicolas Merle ◽  
Aimery de Mallmann ◽  
...  
Keyword(s):  
Olefin Metathesis ◽  
Group Vi ◽  
Metal Compounds

scholarly journals Activation of Low-Valent, Multiply M–M Bonded Group VI Dimers toward Catalytic Olefin Metathesis via Surface Organometallic Chemistry

2020 ◽  
Vol 39 (7) ◽  
pp. 1035-1045 ◽  
Author(s):  
Alon Chapovetsky ◽  
Ryan R. Langeslay ◽  
Gokhan Celik ◽  
Frédéric A. Perras ◽  
Marek Pruski ◽  
...  
Keyword(s):  
Organometallic Chemistry ◽  
Olefin Metathesis ◽  
Group Vi ◽  
Surface Organometallic Chemistry ◽  
Low Valent
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