Homogeneous catalysts for carbon dioxide/hydrogen activation. Alkyl formate production using anionic ruthenium carbonyl clusters as catalysts

1983 ◽  
Vol 105 (18) ◽  
pp. 5937-5939 ◽  
Author(s):  
Donald J. Darensbourg ◽  
Cesar Ovalles ◽  
Magdalena Pala
Keyword(s):  
Carbon Dioxide ◽  
Homogeneous Catalysts ◽  
Hydrogen Activation ◽  
Carbonyl Clusters ◽  
Ruthenium Carbonyl ◽  
Ruthenium Carbonyl Clusters ◽  
Formate Production

Methanation of carbon monoxide and dioxide by supported metal carbonyl clusters

1983 ◽  
Vol 61 (6) ◽  
pp. 1306-1308 ◽  
Author(s):  
H. E. Ferkul ◽  
J. M. Berlie ◽  
D. J. Stanton ◽  
J. D. McCowan ◽  
M. C. Baird
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Metal Carbonyl ◽  
Carbon Monoxide Hydrogenation ◽  
Carbonyl Clusters ◽  
Ruthenium Carbonyl ◽  
Ruthenium Carbonyl Clusters ◽  
Metal Carbonyl Clusters ◽  
Carbon Dioxide Methanation ◽  
Methanation Catalyst

The catalysis of carbon monoxide hydrogenation by supported cobalt and ruthenium clusters is studied, and an unusually specific cobalt methanation catalyst is described. A variety of ruthenium carbonyl clusters catalyzes carbon monoxide methanation, irrespective of support, and Ru3(CO)12 on γ-alumina is found to be a potentially useful carbon dioxide methanation catalyst.

Activation of Open-Cage Fullerenes with Ruthenium Carbonyl Clusters

2014 ◽  
Vol 20 (4) ◽  
pp. 936-940 ◽  
Author(s):  
Chi-Shian Chen ◽  
Yu-Fang Lin ◽  
Wen-Yann Yeh
Keyword(s):  
Carbonyl Clusters ◽  
Ruthenium Carbonyl ◽  
Ruthenium Carbonyl Clusters

Aerobic oxidation of primary benzylic amines to amides and nitriles catalyzed by ruthenium carbonyl clusters carrying N,O-bidentate ligands

2020 ◽  
Vol 49 (11) ◽  
pp. 3480-3487 ◽  
Author(s):  
Xinlong Yan ◽  
Qing Dong ◽  
Ying Li ◽  
Lizhen Meng ◽  
Zhiqiang Hao ◽  
...  
Keyword(s):  
Efficient Method ◽  
Aerobic Oxidation ◽  
Bidentate Ligands ◽  
Carbonyl Clusters ◽  
Ruthenium Carbonyl ◽  
Ruthenium Carbonyl Clusters ◽  
Benzylic Amines

An efficient method for direct oxygenation of primary arylamines to nitriles and amides with switchable selectivity was developed using N,O-bidentate Ru3 clusters as catalysts.

New Ruthenium Carbonyl Clusters Containing Unusual μ5-Sulfido-, μ4-Benzyne-, and Thianthrene-Derived Ligands:  Insertion of Ruthenium into the Thianthrene Ring by C−S Activation

2007 ◽  
Vol 26 (18) ◽  
pp. 4627-4633 ◽  
Author(s):  
Mohammad R. Hassan ◽  
Shariff E. Kabir ◽  
Brian K. Nicholson ◽  
Ebbe Nordlander ◽  
Md. Nazim Uddin
Keyword(s):  
Carbonyl Clusters ◽  
Ruthenium Carbonyl ◽  
Ruthenium Carbonyl Clusters
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