Mechanistic aspects of a homogeneous carbon monoxide hydrogenation catalyst - tetrairidium dodecacarbonyl in molten aluminum chloride-sodium chloride

1983 ◽  
Vol 105 (12) ◽  
pp. 3913-3922 ◽  
Author(s):  
James P. Collman ◽  
John I. Brauman ◽  
Gerald Tustin ◽  
Grady S. Wann
Keyword(s):  
Carbon Monoxide ◽  
Sodium Chloride ◽  
Aluminum Chloride ◽  
Molten Aluminum ◽  
Hydrogenation Catalyst ◽  
Carbon Monoxide Hydrogenation

ChemInform Abstract: ELECTROOXIDATION OF SULFUR IN MOLTEN ALUMINUM CHLORIDE-SODIUM CHLORIDE(63-37 MOLE PERCENT)

1979 ◽  
Vol 10 (20) ◽  
Author(s):  
R. MARASSI ◽  
G. MAMANTOV ◽  
M. MATSUNAGA ◽  
S. E. SPRINGER ◽  
J. P. WIAUX
Keyword(s):  
Sodium Chloride ◽  
Aluminum Chloride ◽  
Molten Aluminum ◽  
Mole Percent

Attempts to heterogenize the Ir4(Co)12-Al2Cl6 homogeneous carbon monoxide hydrogenation catalyst

1989 ◽  
Vol 53 (2) ◽  
pp. 229-245 ◽  
Author(s):  
C.S. Goldstein-Getty ◽  
R.S. Drago ◽  
K.D. Weiss ◽  
J.G. Miller
Keyword(s):  
Carbon Monoxide ◽  
Hydrogenation Catalyst ◽  
Carbon Monoxide Hydrogenation

Spectroelectrochemical Investigation of the Behavior of Tetra-Chloro-p-Benzoquinone in Molten Sodium Chloroaluminates

1994 ◽  
Vol 48 (3) ◽  
pp. 406-409
Author(s):  
E. M. Hondrogiannis ◽  
J. C. Coffield ◽  
D. S. Trimble ◽  
A. E. Edwards ◽  
G. Mamantov
Keyword(s):  
Electron Spin Resonance ◽  
Sodium Chloride ◽  
Electron Spin ◽  
Aluminum Chloride ◽  
Radical Anion ◽  
Molten Aluminum ◽  
Mole Percent ◽  
Molten Sodium ◽  
Spin Resonance ◽  
Uv Visible

The Raman, UV-visible, electron spin resonance spectroscopic, and spectroelectrochemical (SEC) behavior of tetrachloro- p-benzoquinone (chloranil) in molten aluminum chloride/sodium chloride mixtures has been examined. The results support previous findings suggesting that the chloranil is complexed by AlCl3or A12C17– in acidic melts [>50 mole percent (m/o) A1C13], while in basic melts (< 50 m/o A1C13) the chloranil remains uncomplexed. The results further support the previously proposed stepwise one-electron reductions in the acidic melt to produce the radical anion and the dianion. The present work, however, reveals that chloranil is also reduced through two closely spaced one-electron reductions in the basic melt.

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