Rate constants and Arrhenius parameters for the reaction of a primary alkyl radical with tributylgermanium hydride

1983 ◽  
Vol 105 (11) ◽  
pp. 3578-3580 ◽  
Author(s):  
J. Lusztyk ◽  
B. Maillard ◽  
D. A. Lindsay ◽  
K. U. Ingold
Keyword(s):  
Rate Constants ◽  
Alkyl Radical ◽  
Arrhenius Parameters

REACTION OF OXYGEN ATOMS WITH BUTADIENE

1960 ◽  
Vol 38 (11) ◽  
pp. 2187-2195 ◽  
Author(s):  
R. J. Cvetanović ◽  
L. C. Doyle
Keyword(s):  
Pressure Dependence ◽  
Rate Constants ◽  
Room Temperature ◽  
Relative Rate ◽  
Excess Energy ◽  
General Mechanism ◽  
Arrhenius Parameters ◽  
Heats Of Reaction ◽  
Relative Rate Constants ◽  
Oxygen Atoms

Reaction of oxygen atoms with 1,3-butadiene has been investigated at room temperature. It is found that it conforms to the general mechanism established previously for the analogous reactions of monoolefins. Only 1,2-addition occurs, and the addition products, butadiene monoxide and 3-butenal, possess excess energy when formed as a result of high heats of reaction. The pressure dependence of the formation of the addition products yields the values of the "lifetimes" of the initially produced "hot" molecules. The relative rate constants have been determined at 25 and 127 °C and from these the relative values of the Arrhenius parameters have been calculated.

Rate Constants and Arrhenius Parameters for the Reaction of Acyl Radicals with Bu3SnH and (Me3Si)3SiH

1995 ◽  
Vol 14 (6) ◽  
pp. 2672-2676 ◽  
Author(s):  
C. Chatgilialoglu ◽  
C. Ferreri ◽  
M. Lucarini ◽  
P. Pedrielli ◽  
G. F. Pedulli
Keyword(s):  
Rate Constants ◽  
Arrhenius Parameters ◽  
Acyl Radicals

Determination of the Rates of Hydrogen Atom Reaction with NO by a Modulation Technique

1973 ◽  
Vol 51 (3) ◽  
pp. 370-372 ◽  
Author(s):  
R. Atkinson ◽  
R. J. Cvetanović
Keyword(s):  
Nitric Oxide ◽  
Hydrogen Atom ◽  
Phase Shift ◽  
Rate Constants ◽  
Hydrogen Atoms ◽  
Arrhenius Parameters ◽  
Modulation Technique ◽  
The Absolute

A modulation technique has been used to determine from phase shift measurements the absolute values of the rate constants and the Arrhenius parameters of the reaction of hydrogen atoms with nitric oxide.

Sign in / Sign up

Export Citation Format

Share Document